We report the tip-induced superconductivity on the topological semimetal NbSb2, similar to the observation on TaAs2 and NbAs2. Belonging to the same family of MPn 2, all these materials possess similar band structures, indicating that the tip-induced superconductivity may be closely related to their topological nature and share a common mechanism. Further analysis suggests that a bulk band should play the dominant role in such local superconductivity most likely through interface coupling. In addition, the compatibility between the induced superconductivity and tips’ ferromagnetism gives an evidence for its unconventional nature. These results provide further clues to elucidate the mechanism of the tip-induced superconductivity observed in topological materials.
Non-centrosymmetric superconductors have received considerable attention because of their possible possession of unconventional spin-triplet pairing.For this reason,the non-centrosymmetric Re<sub>3</sub>W with <i>α</i> -Mn structure has been widely concerned.However,almost all the previous studies support that the non-centrosymmetric phase of Re<sub>3</sub>W is a conventional weak-coupling s-wave superconductor.Later on,it is proved that Re<sub>3</sub>W has two different superconducting phases,one is the non-centrosymmetric phase and the other has a centrosymmetric hexagonal structure.Thus,a comparative study of these two superconducting phases could provide more information about the effect of non-centrosymmetric structure on the pairing symmetry of Re<sub>3</sub>W.</br>In this paper,point-contact Andreev reflection experiments are carried out on Re<sub>3</sub>W/Au and the data can be well fitted by isotropic s-wave Blonder-Tinkham-Klapwijk (BTK) theory.In combination with our previous researches,we find that both centrosymmetric and non-centrosymmetric phases have similar temperature dependence of superconducting gap (<i>△</i>) with almost the same gap ratio of <i>△</i>/<i>T</i><sub>c</sub>.These results present strong evidence that both phases of Re<sub>3</sub>W are weak coupling Bardeen-Cooper-Schrieffer superconductors.</br>Another interesting finding is that both phases of Re<sub>3</sub>W could easily form an ideal point-contact junction (i.e.,inelastic scatterings at the interface can be ignored) with a normal metal tip.This is manifested as an extremely small broadening factor (<i>Γ</i>) used in the fitting process,and indicates a clean (and possibly transparent) interface.Keeping this in mind,we can assume that the effective barrier (<i>Z</i>) at the interface mainly comes from the mismatch between the Fermi velocity of the superconductor and that of the normal metal,which can be estimated from the formula <i>Z</i><sup>2</sup>=(1-<i>r</i>)<sup>2</sup>/4<i>r</i>,where <i>r</i> is the ratio between those two Fermi velocities.From this formula,we can obtain the Fermi velocity of Re<sub>3</sub>W by using the known value of Au's Fermi velocity and the fitting parameter <i>Z</i> for the Re<sub>3</sub>W/Au point contacts.It is interesting to find that the chemical property of Re<sub>3</sub>W is stable in the atmospheric environment.Even if the samples are exposed to the atmospheric environment for nearly six months,the inelastic scatterings are still very weak,and the superconducting properties are unchanged.</br>Such an exceptional performance of Re<sub>3</sub>W can be utilized to study the physical properties of its counter electrode in a point contact.As an attempt,we build a point contact between Re<sub>3</sub>W and a ferromagnetic Ni tip,and measure its Andreev reflection spectra which are then fitted with a modified BTK model by considering spin polarization.The determined spin polarization of Ni is in good agreement with previously reported result. Moreover,using the Fermi velocities of Re<sub>3</sub>W and Ni,we can calculate the effective barrier to be around 0.3 in the Re<sub>3</sub>W/Ni interface,which coincides with the fitting parameter <i>Z</i>.These results self-consistently demonstrate the validity of the determination of Re<sub>3</sub>W's Fermi velocity and the cleanness/transparency of the studied point-contact interface.
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