In this study, a simple, facile and one-pot solvothermal method was developed for preparation of reduced graphene oxide (RGO) supported hollow Ag@Pt core-shell nanospheres (hAg@Pt), using ethylene glycol (EG) as a reducing agent and sodium dodecyl sulfate (SDS) as a soft template. Control experiments demonstrated that the molar ratios of the Pt-Ag precursors, the amount of SDS, the presence of RGO, and the reaction temperature were critical to the final nanocomposites. The as-prepared hAg@Pt-RGO showed the improved electrocatalytic activity and durability toward ethylene glycol oxidation, which can serve as a promising potential electrocatalyst in direct alcohol fuel cells.
Experimental
MaterialsChloroplatinic acid (H 2 PtCl 6 ), silver nitrate, SDS, graphite powders (8000 mesh), and EG were purchased from Aladdin
PdM (M = Pt, Co, and Ni) nanodendrites were fabricated by a co-reduction strategy. The nanodendrites displayed the enhanced catalytic activities and stabilities for methanol and ethylene glycol oxidation.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.