Phase-change microcapsules with photothermal conversion
capabilities
have been the focus of research in the energy storage field. In this
study, a route is developed to prepare photothermal conversion and
phase-change energy storage microcapsules by copper sulfide-stabilized
Pickering emulsion with dodecanol tetradecyl ester as the phase-change
material (PCM) and melamine formaldehyde resin (MF) as a shell. Spherical
CuS particles with a diameter of approximately 10 nm are first synthesized
by a facile hydrothermal reaction. The obtained CuS nanoparticles
are used not only as a stabilizer but also as a photothermal conversion
material in the preparation of the microcapsules. Then, the PCM microcapsules
are prepared by a one-pot interfacial polymerization route and showed
a well-defined core–shell structure with an average size of
approximately 7 μm. The synthesized microcapsules have a latent
heat of up to 180.3 J/g and an encapsulation efficiency of 81.36%.
Meanwhile, the thermal conductivity of the microcapsules increased
by 115–254% compared to the core material due to the hybrid
shell filled with CuS nanoparticles. The photothermal conversion capacity
of the synthesized microcapsules is measured and calculated to be
up to 85.6%, achieving light-induced phase change and further inducing
the passive thermal cycle. This study provides a potential candidate
for the application of light-induced energy storage microcapsules
in fabric insulation, solar hot water heating systems, and solar thermal
power systems.
In order to maintain thermal comfort in the human body,
photothermal
conversion and energy storage microcapsules were designed, developed,
and applied in a light-assisted thermoregulatory system. The octyl
stearate as a phase change material (PCM) was encapsulated using a
polytrimethylolpropane triacrylate (PTMPTA)/polyaniline (PANI) composite
as the shell, which was synthesized by adding the intermediate half
oxidation state of PANI into the polymerization system of trimethylolpropane
triacrylate (TMPTA). In the PCM microcapsules, the PANI particles
embedded in the shell can convert sunlight into heat energy to feed
the PCM core for energy storage, further realizing the temperature
regulation and solving the problem that the phase change behavior
cannot be triggered in cold environments. The octyl stearate@PTMPTA/PANI
microcapsules exhibit a latent heat of over 103 J/g, good thermal
reliability, and 89.12% photothermal conversion efficiency (PCM microcapsules
(MEPCM) suspension). Owing to the excellent photothermal performance
of the PANI, the thermal energy will be generated under sunshine and
simultaneously transferred to the microcapsules for energy storage.
As a result, the MEPCM-PTMPTA/PANI can not only achieve a higher temperature
than ambient air but also initiate the phase transition process. The
obtained microcapsules were further printed on a T-shirt, and a test
of self-thermoregulation was carried out in winter. The results suggest
that MEPCM-PTMPTA/PANI has good photothermal conversion and temperature
regulation capacity under sunshine and low temperature environments.
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