Copper and cobalt are two major metals used in industry. They play a role in widely many domains like that electricity, chemistry and electrochemistry. They are contained into several minerals like chalcopyrite, carrolite, chalcocite, etc. associated to pyrite. The froth flotation and behaviors of chalcocite and carrolite were investigated through many flotation tests in order to recovery copper and cobalt. This paper investigates the effect of potassium amyl xanthate (PAX) and sodium dibutyl dithiophosphate (DANA) performance on both copper and cobalt recovery in single roughing flotation. The effect of pH on the flotation is proposed. Some parameters were kept constant such as particle size d80=75 μm, pulp density 10% solids, impeller speed 1300 rpm, and PAX doses of DANA (105 g/t per each) as collectors, dose of DF250 (5 drops) as frother, dose of Na 2 SiO 3 (200 g/t) as dispersant and depressant. Only the pulp pH was varied from the natural pH to 11, using Ca(OH) 2 as regulator. According to results, PAX (105 g/t) was found as the best collector for recovery of copper both at natural pH and pH=11. At natural pH, the concentrate was found at 16.1% copper recovery with a yield of 99.63%. At pH=11, the concentrate was found at 16.1% copper recovery with a yield of 99.05%. For the recovery of cobalt, DANA (105 g/t) was found better as the collector at natural pH producing a concentrate at 0.51% cobalt recovery yield of 76.48%. At pH=11, PAX (105 g/t) was found better as the collector. The concentrate was found at 0.91% cobalt with a recovery yield of 85.13%.
A sulfate solution containing 1773.965 mg/L Mn2+, 3216.178 mg/L Mg2+ and 566.254 mg/L Ca2+ was used to perform the maximum recovery of manganese and minimum recovery of magnesium. Carbonate precipitation was used due to the better selectivity for manganese over magnesium and other impurities recovery compared to hydroxide precipitation. Four factors were studied: solution pH value, contact time, reaction temperature and sodium carbonate consumption. Analysis of variance (ANOVA) and response surface methodology (RSM) were used to determine the optimum. Under the optimum conditions, the manganese and magnesium recoveries were the highest and the lowest respectively, while the pH, the time, the temperature and the volume of Na2CO3 were the lowest. The values of the four factors were found as followed: 8.9293, 60.69 min, 77.95°F, and 50.7650 mL respectively. Moreover, the recoveries of manganese and magnesium were 99.9799% and 4.3045% respectively. The results show that optimization using RSM is effective in improving carbonate precipitation of manganese.
Copper and cobalt demand is projected to be increased from here to 2050 and the challenge is to find treat economically minerals which contains those metals. Several tailings from oxide ores throughout the word contain good grades of copper and cobalt that should be recovered by froth flotation. This paper investigates the recovery of copper and cobalt through reprocessing of spiral classifier tailings by determination of specific reagents dosage. The flotation behaviours of malachite and heterogenite were studied through many roughing and cleaning flotation tests in order to recovery most of copper and cobalt. The effect of specific reagents was be varied and others parameters were kept constant. The highest recoveries of both copper and cobalt in rougher concentrate were respectively 82.51% and 72.51% with grades of 12.52% and 0.99% respectively. However, the cleaner concentrate was 24.54 Cu% and 1.38% Co with recoveries of 69.26 % and 40.7% respectively. It was concluded that the reprocessing of spiral classifier tailings through froth flotation is benefit because it recovers most of desired metal and reduces the risk of their presence on environment through.
Copper and cobalt demand is projected to be increased from here to 2050 and the challenge is to find treat economically minerals which contains those metals. Several tailings from oxide ores throughout the word contain good grades of copper and cobalt that should be recovered by froth flotation. This paper investigates the recovery of copper and cobalt through reprocessing of spiral classifier tailings by determination of specific reagents dosage. The flotation behaviours of malachite and heterogenite were studied through many roughing and cleaning flotation tests in order to recovery most of copper and cobalt. The effect of specific reagents was be varied and others parameters were kept constant. The highest recoveries of both copper and cobalt in rougher concentrate were respectively 82.51% and 72.51% with grades of 12.52% and 0.99% respectively. However, the cleaner concentrate was 24.54 Cu% and 1.38% Co with recoveries of 69.26 % and 40.7% respectively. It was concluded that the reprocessing of spiral classifier tailings through froth flotation is benefit because it recovers most of desired metal and reduces the risk of their presence on environment through.
Copper-cobalt oxide ores contain several minerals that are economically treatable by concentration techniques. The most used technique is froth flotation in which selective reagents are used to recover more valuables. It is, therefore, important to examine the optimal doses of those reagents while investigating the behaviors of minerals at the same time. This study explored the influence of lead nitrate Pb(NO3)2 on the froth flotation of oxide ore to increase valuable metals recoveries. Four factors were investigated including Pb(NO3)2 dosage, its conditioning, its addition dose in the 2nd fraction, and sulfidiser dosage. Other parameters were kept constant. The optimum was found at 25 g/t of Pb(NO3)2, conditioning together with sodium silicate (Na2SiO3) for 5 min, the addition of 5 g/t of Pb(NO3)2 in the 2nd fraction, and 3,000 g/t of sulfidiser. Recoveries in concentrates were 79.51 % Copper (Cu) and 60.27 % Cobalt (Co), with grades of 9.49 and 0.67 %, respectively. The conclusion was that the use of Pb(NO3)2 can considerably improve copper and cobalt recoveries.
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