Spin-crossover (SCO) is generally regarded as a spectacular molecular magnetism in 3d-3d metal complexes and holds great promise for various applications such as memory, displays, and sensors. In particular, SCO materials can be multifunctional when a classical light- or temperature-induced SCO occurs along with other cooperative structural and/or electrical transport alterations. However, such a cooperative SCO has rarely been observed in condensed matter under hydrostatic pressure (an alternative external stimulus to light or temperature), probably due to the lack of synergy between metal neighbors under compression. Here, we report the observation of a pressure-driven, cooperative SCO in the two-dimensional (2D) honeycomb antiferromagnets MnPS and MnPSe at room temperature. Applying pressure to this confined 2D system leads to a dramatic magnetic moment collapse of Mn (d) from S = 5/2 to S = 1/2. Significantly, a number of collective phenomena were observed along with the SCO, including a large lattice collapse (∼20% in volume), the formation of metallic bonding, and a semiconductor-to-metal transition. Experimental evidence shows that all of these events occur in the honeycomb lattice, indicating a strongly cooperative mechanism that facilitates the occurrence of the abrupt pressure-driven SCO. We believe that the observation of this cooperative pressure-driven SCO in a 2D system can provide a rare model for theoretical investigations and lead to the discovery of more pressure-responsive multifunctional materials.
The properties of a silicone fluid with initial viscosity of 1 cst as a pressure transmitting medium for diamond anvil cells have been determined by ruby R1 line broadening and R1-R2 separation measurements to 64 GPa at ambient temperature. By these criteria, the silicone fluid is as good a pressure medium as a 4:1 methanol:ethanol mixture at low pressures to about 20 GPa, and is better than the mixture at higher pressures. Although argon media are better than the silicone at pressures to 30 GPa, this silicone behaves as well as argon at higher pressures. Furthermore, the silicone is easier to load than argon and is almost chemically inert.
The structural phase stability of 1,1-diamino-2,2-dinitroethylene (FOX-7) has been studied up to 10 GPa through isothermal compression at 100 °C and 200 °C using synchrotron mid- and far-infrared spectroscopy. During isothermal compression at 100 °C changes are observed in vibrational spectra with increase in pressure that are indicative of significant distortion to monoclinic α phase or a possible structural transformation to a high pressure α(') phase at 2.2 GPa and α(") phase at 6.1 GPa. At 200 °C, for the far- and mid-IR regimes, the similar changes were observed at 2.1 (2.0) GPa and 5.3 (5.5) GPa, respectively. The observed change is nearly isobaric, consistent with previously reported high pressure and room temperature values, up to the highest temperature of 200 °C reached in our experiments. Over the total P-T range investigated, up to ∼10 GPa and 200 °C, we observed no evidence of sample decomposition. The observed changes are partially reversible with only slight evidence of the high pressure distortion remaining upon complete decompression. Additional isobaric heating at 1.07 GPa was performed in the mid-IR regime, which clearly revealed an onset of decomposition at 360 °C. Further x-ray or neutron diffraction, which are needed to fully resolve the cause of observed changes above 2 and 5 GPa, are ongoing.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.