Three photocatalyst inks based on the redox dyes, Resazurin (Rz), Basic Blue 66 (BB66) and Acid Violet 7 (AV7, are used to assess the photocatalytic activities of a variety of different materials, such as commercial paint, tiles and glass and laboratory made samples of sol-gel coated glass and paint, which collectively exhibit a wide range of activities that cannot currently be probed by any one of the existing ISO tests. Unlike the ISO tests, the ink tests are fast (typically < 10 min), simple to employ and inexpensive. Previous work indicates that the Rz ink test at least correlates linearly with other photocatalytic tests such as the photomineralisation of stearic acid. The average time to bleach 90% of the key RGB colour component of the ink (red for Rz and BB66 inks) and green for AV7 ink) is determined, ca. 11% and ca 21%, respectively, which compare well with those reported for the current ISO tests. Additional work on commercial self-cleaning glass using an Rz ink showed that the change in the red component of the RGB image of the ink correlated linearly with that of the change of absorbance (at 608 nm) (as measured using UV/Vis spectroscopy) and the change in the a* component of the Lab colour analysis of the ink, as measured using diffuse reflectance spectroscopy. As a consequence, all three methods generate the same ttb(90).The advantages of the RGB digital image analysis method are discussed briefly.
A rapid, semi-quantitative, inexpensive method, using a simple digital scanner and an indicator ink, suitable for use in the laboratory, or in the field, for assessing the photocatalytic activity of commercial photocatalytic self-cleaning materials such as glass, is described. The repeatability of the current method is found to be high and better than many of the previously reported ISO photocatalyst tests.
A novel 1D nanotubular TiO2/MoS2 nanosheet heterostructure possesses synergistic effects that yield superior photon-to-electron conversion and photocatalysis.
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