Abstract. The aim of the study was to determine the potential for the application of dust from steel plant as an effective sorbent for removing Cr(III) and Cr(VI) in the form of simple and complex ions -Acid Blue 193 dye from aqueous solutions. Three isotherms models were used to interpret the experimental results namely: Langmuir, Freundlich, and DubininRadushkevich. Estimated equations parameters allowed to determine the binding mechanism. Based on laboratory studies it was found that the dust was characterized by high sorption capacities for Cr ions and dye from the aqueous solution. The sorption capacity of the dust for Cr(III) and Cr(VI) ions depended on the degree of oxidation, pH of solution and kind of anion and changed in series: Cr(III)-Cl pH=5.0> Cr(III)-SO4 pH=5.0> Cr(III)-Cl pH=3.0> Cr(III)-SO4 pH=3.0> Cr(VI) pH=5.0> Cr(VI) pH=3.0. Dust was also characterized by a high maximum sorption capacity of dye at a range of 38.2 -91.7 mg/g, depending on the dose of dust. Based on the study it was found that dust from a steel plant, containing iron oxides, can be used as low-cost and effective sorbent to remove pollutions containing chromium ions, especially from acidic wastewater.
The migration of metals and metalloids between bottom sediments and water and the other way round is a complex process. Understanding those mechanisms is essential for recognizing transformations taking place in water reservoir ecosystems. The objective behind the following study was to define time and spatial correlations in the changes in total concentrations of selected elements (Cr, Zn, Co, Mn, Cu, Ni, Pb, As, Ba, Sb, Sr and V) in waters and bottom sediments from two water reservoirs located in Upper Silesia (Poland), i.e., Pławniowice and Dzierżno Małe. The research was carried out to demonstrate whether the bottom sediments deposited in the discussed reservoirs could pose an environmental threat due to the possible release of toxic metals and metalloids into the pelagic zone. The obtained results constitute material helping to describe the bioavailability of particular elements. They also expose the existing environmental threats for such water reservoirs and their users.
Abstract. This study was carried out to characterize three aldehydes of health concern (formaldehyde, acetaldehyde, and acrolein) at a three sites in Silesian region (Poland) in January and June 2015. Aldehydes in polluted atmospheres comes from both primary and secondary sources, which limits the control strategies for these reactive compounds. Average aldehyde concentration in summer period lies in range from 3.13 µg/m 3 to 10.43 µg/m 3 , in winter period in range from 29.0 µg/m 3 to 32.2 µg/m 3 . Acetaldehyde was dominant compound in winter period, in summer formaldehyde concentration was highest of all determined aldehydes.
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