Biaxially oriented polypropylene (BOPP) is a highly transparent polymer defined by excellent mechanical and barrier properties applicable in the food packaging industry. However, its low surface free energy restricts its use in many industrial processes and needs to be improved. The presented study modifies a BOPP surface using two different atmospheric-pressure plasma sources operating in ambient air and capable of inline processing. The volume dielectric barrier discharge (VDBD) and diffuse coplanar surface barrier discharge (DCSBD) were applied to improve the wettability and adhesion of the 1–10 s treated surface. The changes in morphology and surface chemistry were analyzed by SEM, AFM, WCA/SFE, and XPS, and adhesion was evaluated by a peel force test. Comparing both plasma sources revealed their similar effect on surface wettability and incorporation of polar functional groups. Additionally, higher surface roughness in the case of VDBD treatment contributed to slightly more efficient adhesion in comparison to DCSBD. Although we achieved comparable results for both plasma sources in the term of enhanced surface wettability, degree of oxidation, and stability of induced changes, DCSBD had less effect on the surface deterioration than VDBD, where surface structuring caused an undesirable haze.
Die optische Meßtechnik zeichnet sich aus durch ihre hohe Geschwindigkeit, durch die rück-wirkungsfreie Datengewinnung und durch die hohen Auflösungen, die sie erreichen kann. Allerdings zeigten sich in der Vergangenheit oft große Abweichungen zu taktilen Verfahren, wenn optisch rauhe Oberflächen vermessen wurden. In diesem Beitrag möchten wir zeigen, daß sowohl die konfokale Mikroskopie als auch die Weißlichtinterferometrie geeignet sind, hochaufgelöste und vor allen Dingen vergleichbare Ergebnisse zu liefern. Vorgestellt werden die Verfahren, Ergebnisse an technischen Proben und ein Ausblick, wie Materialaspekte bei der Messung berücksichtigt werden können, indem zusätzlich ellipsometrische Winkel gemessen werden.Optical measurement techniques offer a high data acquisition rate, a non-contact mode, and a high resolution. But there are often large differences in the results obtained by optical and tactile sensors if rough surfaces are investigated. In this paper we demonstrate that confocal microscopy and white-light interferometry offer high resolution measurements on engineering surfaces and we show that the results are comparable to standard tactile sensors. The sensors are presented as well as results obtained on engineering surfaces. Material aspects are analysed by additional ellipsometric measurements.
Nanofiber membranes are made of synthetic polymers mainly by electrospinning technology. The key point for creating a functional nanofiber membrane for water and air filters is to meet basic key properties such as filtration efficiency, mechanical resistance, and resistance to fouling and chemicals. Design and manufacturing of the advanced nanofiber-based filters urgently require new environment-friendly and cost-effective surface treatments without the use of organic solvents and caustic solutions. To address this need, as an alternative, the atmospheric-pressure plasma treatment offers to be used for surface activation of polymer textile materials serving as a substrate for electrospun nanofiber. Nanofiber carriers represented by polypropylene non-woven were pre-treated by dielectric barrier discharge in continuous mode to improve the adhesion between the produced nanofibers and substrate. The increased adhesive forces to carrier substrate were confirmed by two peeling tests. The fact that the robust and effective atmospheric-pressure diffuse coplanar surface barrier discharge technology, primarily developed and optimized for the plasma treatment of textile and fibrous material, can be easily implemented in the industrial production lines predetermines this technology for in-line a large throughput manufacturing of advanced nanofiber-based filters.
The Multi-hollow Surface Dielectric Barrier Discharge (MSDBD) generated in ambient air at atmospheric pressure was used to treat maize, pea, wheat and parsley seeds. Plasma exposure was applied as a pre-treatment before the seeds coating with agrochemicals. The aim of this study was to decrease the dustiness of coated seeds using plasma pre-treatment. The optimization process of plasma treatment parameters for individual seed species consisted of choosing a suitable exposure time (20 s, 60 s) and airflow (10 L/min, 15 L/min). The plasma made the seeds' surface more hydrophilic; therefore, better agrochemicals adhesion was achieved on the seeds' surface. Wettability improvement was demonstrated via water uptake of seeds and apparent contact angle change. Ambient air plasma at a 15 L/min flow rate was measured using optical emission spectroscopy, and the values of vibrational (3000 K) and rotational (347 K) temperatures were obtained from spectra simulation. The surface temperature of the MSDBD ceramics plate was measured with a thermal camera for different gas flow rates and constant input power of 30 W because the temperature is crucial parameter for seed treatment. The surface morphology was not affected due to plasma treatment, even for a longer exposure time. A significant decrease in dustiness measured according to the Heubach method was achieved for pea (57.1%) and parsley (41.4%) seeds. A lower decrease in dustiness was registered in the case of wheat (14.6%) and maize (17%) seeds. The results showed that MSDBD plasma generated in the air at optimized conditions is able to decrease the coated seed dustiness regardless of seed type and size, while seeds germination and surface coverage percentage remained unchanged.
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