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Heteroaggregation (or heterocoagulation) rate constants have been measured in mixtures of well-characterized colloidal particles of opposite charge with multiangle static and dynamic light scattering. This technique permits routine measurements of absolute heteroaggregation rate constants, also in the presence of homoaggregation. Particularly with multiangle dynamic light scattering, one is able to estimate absolute heteroaggregation rate constants accurately in the fast aggregation regime for the first time. Heteroaggregation rate constants have also been measured over a wide range of parameters, for example, ionic strength and different surface charge densities. Amidine latex particles, sulfate latex particles, and silica particles have been used for these experiments, and they were well characterized with respect to their charging and homoaggregation behavior. It was shown that heteroaggregation rate constants of oppositely charged particles increase slowly with decreasing ionic strength, and provided the surface charge is sufficiently large, the rate constant is largely independent of the surface charge. These trends can be well described with DLVO theory without adjustable parameters.

Confronting grand canonical titration Monte Carlo simulations (MC) with recently published titration and charge reversal (CR) experiments on silica surfaces by Dove and Craven (Dove, P. M.; Craven, C. M. Geochim. Cosmochim. Acta 2005, 69, 4963-4970) and van der Heyden et al. (van der Heyden, F. H. J.; Stein, D.; Besteman, K.; Lemay, S. G.; Dekker, C. Phys. Rev. Lett. 2006, 96, 224502), we show that ion-ion correlations quantitatively explain why divalent counterions strongly promote surface charge which, in turn, eventually causes a CR. Titration and CR results from simulations and experiments are in excellent agreement without any fitting parameters. This is the first unambiguous evidence that ion-ion correlations are instrumental in the creation of highly charged surfaces and responsible for their CR. Finally, we show that charge correlations result in "anomalous" charge regulation in strongly coupled conditions in qualitative disagreement with its classical treatment.

Non-uniformity of superconductor properties, e.g. a critical current reduction close to the edge of a coated conductor (CC) tape could degrade its performance in some power applications. Reliable characterization of such non-uniformity and understanding of its mechanism requires investigation of the character and causes of degradation. In this paper spatial distribution of critical current density across the width of a CC tape is studied. Three different experimental methods allowing estimation of the local current density were utilized for this purpose: (i) magnetic field mapping above the tape through which a DC current is flowing, (ii) measurement of the critical current of separate strips prepared by patterning of the CC tape, and (iii) magnetization measurements of the pieces cut from various positions within the tape width. Very good agreement between the results obtained by these methods was found, showing a reduction of the critical current density at the tape edges with respect to its centre. Moreover, structural investigation by scanning electron microscopy revealed a correlation between the morphology and the critical current density across the tape width. Insertion of such real non-uniform distribution of critical current density into AC loss calculation resulted in a dramatic improvement in the agreement with experimental results.

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