MTBE (methyl tert-butyl ether) represents a rising threat to the environment, especially drinking water, and its effective removal (with all by-products) is necessary. Even a very low concentration of MTBE makes the water undrinkable; therefore, an effective treatment has to be developed. This work is focused on MTBE photocatalytic oxidation in presence of various TiO2 photocatalysts with different phase composition prepared by different methods. It was confirmed the phase composition of TiO2 had the most significant influence on the photocatalytic degradation of MTBE. The rutile phase more easily reduces adsorbed oxygen by photogenerated electrons to superoxide radical, supporting separation of charge carriers. The presence and concentrations of by-products have to be taken into account as well. The conversion of total organic carbon (TOC) was used for the comparison, 40% of TOC was removed after 1 h of irradiation in presence of TiO2–ISOP–C/800 photocatalyst composed of anatase and rutile phase.
In this article we assess the impact of water flow system and precipitation on choose hydro chemical parameter in water-bearing subside areas. Key findings of this study are significant correlation coefficient values obtained from the precipitation amount and occurrence of total phosphorus and phosphates. Therefore the significant effect of other anthropogenic activities on water reservoirs was excluded. The conclusion of this study is that inflowing water (in the case of relatively clean streams) and precipitation can have a positive influence on hydrochemical parameters in water-bearing subside areas and generally contribute to dilution.
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