As the world becomes more urbanized, concerns over the urban heat island (UHI) are more pronounced. Increased urban temperatures have a negative affect on the natural and human environment by producing increased energy usage and smog formation. Pervious concrete pavement is one technology that may help mitigate increased urban temperatures. Temperature data from an instrumented site in Iowa and heat storage phenomena for various weather patterns are presented. The site contains both pervious concrete pavement with a solar reflectance index (SRI) of 14 and traditional concrete pavement with an SRI of 37. Leadership in Energy and Environmental Design (LEED) accepted a high SRI (>29) as one method to characterize a cool surface. Heat capacities of both systems were studied along with a sensitivity analysis of the inputs. The research supports the conclusion that even though pervious concrete may have a much lower SRI than traditional concrete made with similar materials, it can be considered a cool pavement option. In addition, daytime rainfalls combined with the internal high surface area result in significantly more removal of stored heat from the system, with a more rapid mitigation of UHI impacts and reduction in the potential for thermal shock from impervious surface runoff.

Macro-defect-free (MDF) cement is fabricated from a calcium aluminate cement and a poly(viny1 alcohol-acetate) (PVA) copolymer. For the composites studied, it was determined that the interphase regions comprised 63 vol% of the total binder content, while the bulk PVA regions comprised 37 vol% of this phase. Mercury intrusion porosimetry showed that a bimodal pore size distribution developed as binder was removed in increasing amounts from heattreated samples. Larger pores with a characteristic diameter above 30 nm resulted from the removal of bulk PVA, whereas smaller pores approximately 5 nm in size resulted from the removal of water and PVA from the interphase regions. Simulation results obtained from a hard-corehoftshell continuum percolation model of the MDF microstructure indicate that both the bulk PVA and interphase regions form percolative pathways through the system. Dramatic changes in both moisture absorption kinetics and flexural strength were observed only when a percolative network of larger pores was present in these composites. Hence, the bulk polymer regions are the dominant transport pathway for moisture in MDF cement. Based on this knowledge, processing guidelines have been developed to improve the moisture resistance of these materials.

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