The new alloys of the La-Mg-Ni (Ni=ðLa þ MgÞ ¼ 3{4) system absorb and desorb hydrogen at room temperature, and their hydrogen storage capacities are greater than those of conventional AB 5 -type alloys. We investigated the crystal structures of the
An α-cyanostilbene crystal showing optical nonlinearity was examined to be
compared with a non-optically active crystal, with emphasis on the structural aspect.
It was suggested that the introduction of bulky substituents such dimethylamino and
methoxy groups into the cyanostyrene conjugation system was effective to get macroscopic
optical nonlinearity, based on the chemical synthesis and structural analysis. It was
also stressed that the quadrupole interaction in α-cyanostilbenes was one of the important
factors responsible for a nonsymmetric molecular arrangement for the second order optical nonlinearity.
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