Thin film networks of multiwalled carbon nanotubes (MWCNTs) were prepared by exerting chemically induced capillary forces upon the nanotubes. During this process MWCNTs undergo a transformation from being a vertically aligned structure to an interlocking resistive network of interconnected nanotubes, whose main feature is a regular three-dimensional (3D) sieve architecture. Due to their structural characteristics at the nanoscale level, 3D-MWCNT-based networks are in principle ideal candidates for scaffolds/matrices in tissue engineering. Their potential application in this field was confirmed by extensive growth, spreading, and adhesion of the common mouse fibroblast cell line L929.
The use of plasmonic metal nanoparticles as photosensitizers has undergone a strong development in the last few years given their ability to increase the activity of semiconductors into the visible and near infrared regions. The present work reports an experimental and theoretical study on the critical influence that shape anisotropy of gold nanoparticles exerts on the photocatalytic performance of Au-TiO2 nanoarchitectures. The obtained results show
A new class of highly fluorescent, photostable, and magnetic core/shell nanoparticles in the submicrometer size range has been synthesized from a modified Stöber method combined with the layer‐by‐layer (LbL) assembly technique. Luminescent magnetic nanoparticles are prepared via two main steps. The first step involves controlled addition of tetraethoxysilane to a dispersion of Fe3O4/γ‐Fe2O3 nanoparticles, which are thereby homogeneously incorporated as cores into monodisperse silica spheres. The second step involves the LbL assembly of polyelectrolytes and luminescent CdTe quantum dots onto the surfaces of the silica‐coated magnetite/maghemite particles, which are finally covered with an outer shell of silica. These spherical particles have a typical diameter of 220 ± 10 nm and a saturation magnetization of 1.34 emu g–1 at room temperature, and exhibit strong excitonic photoluminescence. Nanoparticles with such a core/shell architecture have the added benefit of providing a robust platform (the outer silica shell) for incorporating diverse functionalities into a single nanoparticle.
CdSe and CdSe@CdS semiconductor nanocrystals have been synthesized in aqueous solutions, using sodium
citrate as a stabilizer. Although initially these quantum dots display photoluminescence with very low quantum
yields, upon prolonged illumination with visible light, enhancements up to 5000% have been measured. This
leads to aqueous quantum dots with high luminescence, which can have important implications in biological
and other applications. A distinct correlation between the photocorrosion process and the photoactivation
process is observed. The primary reason for luminescence enhancement is considered to be the smoothing of
the CdSe core surface. Importantly, even stronger activation was observed in silica- and CdS-coated
nanocolloids where the CdSe core was expected to be shielded from photocorrosion. Preferential adsorption
of oxygen molecules in the porous silicate shell accelerates the photocorrosion process. In CdS-coated particles,
incomplete coating of the original particles is postulated, which is accompanied by the reforming of the CdS
coat because of ionic diffusion at the interface on the newly opening areas with smoother surfaces.
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