We investigate the nonlinear regime of charge and energy transport through Coulomb-blockaded quantum dots. We discuss crossed effects that arise when electrons move in response to thermal gradients (Seebeck effect) or energy flows in reaction to voltage differences (Peltier effect). We find that the differential thermoelectric conductance shows a characteristic Coulomb butterfly structure due to charging effects. Importantly, we show that experimentally observed thermovoltage zeros are caused by the activation of Coulomb resonances at large thermal shifts. Furthermore, the power dissipation asymmetry between the two attached electrodes can be manipulated with the applied voltage, which has implications for the efficient design of nanoscale coolers. [8,9]. Importantly, nonlinearities and rectification mechanisms that lead to the phenomena reported in Refs. [1,2] can be more easily tested in small conductors with strongly energy-dependent densities of states [3,[10][11][12][13][14][15][16][17][18][19][20][21][22]. We emphasize that there is a close relation between the thermopower of a junction and its heat dissipation properties, as demonstrated in Refs. [23][24][25] for the linear regime of transport. Therefore, ascertaining the conditions under which thermovoltages acquire a significant nonlinear contribution has broader implications for power generation and cooling applications [26].We begin our discussion by noticing that vanishing thermovoltages imply the existence of zero thermocurrent states. Unlike voltage-driven currents, which have a definite sign for a bias voltage V > 0 and never cross the V axis for normal conductors (an exception is the Hall resistance of an illuminated two-dimensional electron gas [27]), electric transport subjected a thermal gradient θ displays regions of positive or negative thermocurrents depending on the thermopower sign (positive for electronlike carriers, negative for holelike ones [28]). Nevertheless, this is not sufficient for the thermocurrent to cross the θ axis since the thermopower is constant in linear response. Therefore, a strongly negative

We investigate the nonequilibrium transport properties of a double quantum dot system connected in parallel to two leads, including intradot electron-electron interaction. In the absence of interactions the system supports a bound state in the continuum. This state is revealed as a Fano antiresonance in the transmission when the energy levels of the dots are detuned. Using the Keldysh nonequilibrium Green's function formalism, we find that the occurrence of the Fano antiresonance survives in the presence of Coulomb repulsion. We give precise predictions for the experimental detection of bound states in the continuum. First, we calculate the differential conductance as a function of the applied voltage and the dot level detuning and find that crossing points in the diamond structure are revealed as minima due to the transmission antiresonances. Second, we determine the thermoelectric current in response to an applied temperature bias. In the linear regime, quantum interference gives rise to sharp peaks in the thermoelectric conductance. Remarkably, we find interaction induced strong current nonlinearities for large thermal gradients that may lead to several nontrivial zeros in the thermocurrent. The latter property is especially attractive for thermoelectric applications.

The helical distribution of the electronic density in chiral molecules, such as DNA and bacteriorhodopsin, has been suggested to induce a spin-orbit coupling interaction that may lead to the so-called chirality-induced spin selectivity (CISS) effect. Key ingredients for the theoretical modelling are, in this context, the helically shaped potential of the molecule and, concomitantly, a Rashba-like spin-orbit coupling due to the appearance of a magnetic field in the electron reference frame. Symmetries of these models clearly play a crucial role in explaining the observed effect, but a thorough analysis has been largely ignored in the literature. In this work, we present a study of these symmetries and how they can be exploited to enhance chiral-induced spin selectivity in helical molecular systems.

We consider a strongly interacting quantum dot connected to two leads held at quite different temperatures. Our aim is to study the behavior of the Kondo effect in the presence of large thermal biases. We use three different approaches, namely, a perturbation formalism based on the Kondo Hamiltonian, a slave-boson mean-field theory for the Anderson model at large charging energies and a truncated equation-of-motion approach beyond the Hartree-Fock approximation. The two former formalisms yield a suppression of the Kondo peak for thermal gradients above the Kondo temperature, showing a remarkably good agreement despite their different ranges of validity. The third technique allows us to analyze the full density of states within a wide range of energies. Additionally, we have investigated the quantum transport properties (electric current and thermocurrent) beyond linear response. In the voltage-driven case, we reproduce the split differential conductance due to the presence of different electrochemical potentials. In the temperature-driven case, we observe a strongly nonlinear thermocurrent as a function of the applied thermal gradient. Depending on the parameters, we can find nontrivial zeros in the electric current for finite values of the temperature bias. Importantly, these thermocurrent zeros yield direct access to the system's characteristic energy scales (Kondo temperature and charging energy).