Studies of rainfall isotopic composition in the Iberian Peninsula are scarce, and to date, none of them have provided analyses of the triple oxygen isotopes, preventing from the complete understanding of current atmospheric processes in this region. We investigate the rainwater δ17O, δ18O, and δD and derived parameters 17O-excess and d-excess in a mountain site in the Central South Pyrenees (Villanúa, Huesca, Spain) to identify the main factors (regional and local) controlling the isotopic composition of precipitation at event scale. The samples were collected on a rainfall-event basis during 2 years (from July 2017 to June 2019), and meteorological variables [temperature, relative humidity (RH), and rainfall amount] were monitored at the sampling site. The δ17O, δ18O, and δD values were higher during summer and lower during the rest of the year. In contrast, the 17O-excess and d-excess were lower during summer and higher during the remaining months. We found that the isotopic parameters are weakly correlated with rainfall amount during each event, but they strongly depend on changes in air temperature and moderately on RH. We consider other factors affecting the isotopic composition of rainfall events that resulted to have an important role, such as the influence of the moisture source and trajectory throughout the variations in the synoptic pattern during rainfall events. This dataset can be useful for further comprehensive atmospheric and hydrological studies, with application to paleoclimatic investigations.
The rate and consequences of future high latitude ice sheet retreat remain a major concern given ongoing anthropogenic warming. Here, new precisely dated stalagmite data from NW Iberia provide the first direct, high-resolution records of periods of rapid melting of Northern Hemisphere ice sheets during the penultimate deglaciation. These records reveal the penultimate deglaciation initiated with rapid century-scale meltwater pulses which subsequently trigger abrupt coolings of air temperature in NW Iberia consistent with freshwater-induced AMOC slowdowns. The first of these AMOC slowdowns, 600-year duration, was shorter than Heinrich 1 of the last deglaciation. Although similar insolation forcing initiated the last two deglaciations, the more rapid and sustained rate of freshening in the eastern North Atlantic penultimate deglaciation likely reflects a larger volume of ice stored in the marine-based Eurasian Ice sheet during the penultimate glacial in contrast to the land-based ice sheet on North America as during the last glacial.
Abstract. For the first time, this article presents a large dataset of
precipitation isotopic measurements (δ18Op and δ2Hp) sampled every day or 2 d from seven sites on a
west-to-east transect across northern Spain for 2010–2017. The main aim of
this study is to (1) characterize the rainfall isotopic variability in
northern Spain at daily and monthly timescales and (2) assess the
principal factors influencing rainfall isotopic variability. The relative
role of air temperature and rainfall in determining the stable isotope
composition of precipitation changes along the west-to-east transect, with
air temperature being highly correlated with δ18Op at daily and
monthly timescales, while a few sites along the transect show a significant
negative correlation with precipitation. The highest air temperature–δ18Op dependency is found for a station located in the Pyrenees.
Frontal systems associated with North Atlantic cyclones are the dominant
mechanism inducing precipitation in this region, particularly in winter.
This study allows an exploration of the role of air mass source and
trajectory in determining the isotopic composition of rainfall in northern
Iberia by characterizing the moisture uptake for three of the seven
stations. The importance of continental versus marine moisture sources is
evident, with clear seasonal and spatial variations. In addition, the type
of precipitation (convective versus frontal rainfall) plays a key role, with
convective rainfall associated with higher δ18Op values.
This comprehensive spatiotemporal approach to analyzing the rainfall
isotopic composition represents another step forward towards developing a
more detailed, mechanistic framework for interpreting stable isotopes in
rainfall as a paleoclimate and hydrological tracer.
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