In this paper, we consider an optimal control problem in equilibrium thermodynamics of gases. Thermodynamic state of the gas is given by a Legendrian submanifold in a contact thermodynamic space. Using Pontryagin's maximum principle we find a thermodynamic process on this submanifold such that the gas maximizes the work functional. For ideal gases, this problem is shown to be integrable in Liouville's sense and its solution is given by means of action-angle variables. For real gases considered as a perturbation of ideal ones, the integrals are given asymptotically. *

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In this paper we study a 3-dimensional filtration of real gases described by Redlich-Kwong equations of state. Thermodynamical states are considered as Legendrian (Lagrangian) submanifolds in contact (symplectic) space. Connection between singularities of their projection on the space of intensive variables and phase transitions is shown. Explicit formulae for the Dirichlet boundary problem are given and the distribution of phases in space is shown. *

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