Zircons and other heavy minerals (corundum, rutile, ilmenite, magnetite, sillimanite) are identified in the Nsanaragati gem corundum placer deposit, in the western part of the Mamfe sedimentary basin, SW Cameroon. These alluvial minerals have different morphological characteristics and zircons, in particular, vary mostly in colour and shape. They are reddish, brownish, yellowish, pink or colourless. These minerals form rounded and sub-rounded alluvial grains, prismatic, pyramidal or dipyramidal crystals. Reddish zircons retain their original crystallographic shape. Trace element and U-Pb isotopic geochemical analyses of these reddish zircons, using the LA-ICP-MS method give significant Hf (4576-6334 ppm), Th (46-1565 ppm) and U (66-687 ppm) contents, with Th/U ratio ranging from 0.6 to 3.0. The 206 Pb/ 238 U corrected mean age gave 12.39 Ϯ 0.55 Ma, which characterizes an Upper Cenozoic (Serravallian) magmatic event. The zircons are probably sourced from a magmatic field in the South eastern boundary of the Cross River Formation. The Cameroon Volcanic Line of basaltic and alkaline lavas and intrusions which lie east of the Mamfe Basin mostly range in age from 37 Ma to <1 Ma. The zircons may also relate to the Mount Bambouto plateau lavas which lie northeast of the Mamfe sedimentary basin and have an eruptive age range of 21-14 Ma. The oldest Nsanaragati reddish zircon ages overlap within error with the end stages of the Bambouto eruptions. This eruptive or a related episode provides a potential source for megacrystic reddish zircons within the Nsanagarati placer deposit.
Banded iron formations (BIFs) are the most significant source of iron in the world. In this study, we report petrographic and geochemical data of the BIF from the Meyomessi area in the Ntem Complex, southern Cameroon, and discuss their genesis and the iron enrichment process. Field investigations and petrography have revealed that the studied BIF samples are hard; compact; weakly weathered; and composed of magnetite, subordinate quartz, and geothite. The geochemical composition of the whole rock reveals that iron and silica represent more than 98 wt% of the average composition, whereas Al2O3, TiO2, and high‐field strength elements (HFSE) contents are very low, similar to detritus‐free marine chemical precipitates. The total iron (TFe) contents range from 48.71 to 65.32 wt % (average of 53.29 wt %) and, together with the low concentrations of deleterious elements (0.19 wt % P on average), are consistent with medium‐grade iron ores by global standards. This interpretation is confirmed by the SiO2/Fe2O3total versus (MgO + CaO + MnO)/Fe2O3total discrimination plot in which most of the Meyomessi BIF samples fall in the field of medium‐grade siliceous ore. Only one sample (MGT94) plots in the high‐grade magnetite–geothite ore domain. The high Fe/Ti (376.36), Fe/Al (99.90), and Si/Al (29.26) ratios of the sample are consistent with significant hydrothermal components. The rare earth elements (REE) contents of the studied BIF samples are very low (∑REE: 0.81–1.47 ppm), and the Post‐Archaean Australian Shale (PAAS)‐normalized patterns display weak positive Eu anomalies (Eu/Eu*: 1.15–1.33), suggesting a syngenetic low‐temperature hydrothermal solutions, similar to other BIF worldwide. However, the Meyomessi BIFs show high Fe contents when compared to the other BIFs. This indicates an epigenetic mineralization process affected the Meyomessi BIF. From the above results and based on the field and analytical data, we propose that the genetic model of iron ores at the Meyomessi area involves two stages of the enrichment process, hypogene enrichment of BIF protore by metamorphic and magmatic fluids followed by supergene alteration as indicated by the presence of goethite in the rocks.
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