Dependence of growth
rates of {100} sodium chlorate crystal faces
on solution supersaturation in the range of 0.44–1.32% was
analyzed. It has been shown that the growth rate dispersion does not
have a consequence only in the growth parameter differences predicted
by specific crystal growth theory but that individual crystal faces
may grow with different mechanisms under the same experimental conditions.
The majority of the observed {100} sodium chlorate crystal faces grew
in accordance with the power law
R ∼
σ
n
, whereas approximately one-third of them grew
in accordance with BCF or Chernov’s theories. Possible reasons
for this as well as for the coexistence of crystal faces, which grew
with different mechanisms under the same conditions, have been discussed.
The results of the study of the influence of a static magnetic field of 55 ± 3 mT on the growth rates of diamagnetic sodium chlorate crystals in the direction ⟨100⟩ will be presented. Two groups of experiments were performed in the same solution supersaturation range of 0.89−1.78%, the first in zero field conditions, and the second in an applied magnetic field. The results show that crystals nucleated and grown in a static magnetic field have higher mean growth rates in the ⟨100⟩ direction than crystals in a zero field. Also, X-ray analyses suggest that crystals nucleated and grown in a magnetic field may have a higher lattice constant. Possible mechanisms and possible reasons for these phenomena are discussed.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.