The removal of Cr(III) ions and methylene blue (MB) from aqueous solutions by xanthated corn cob (xCC) in batch conditions was investigated. The sorption capacity of xCC strongly depended of the pH, and increase when the pH rises. The kinetics was well fitted by pseudo-second-order and Chrastil's model. Sorption of Cr(III) ions and MB on xCC was rapid during the first 20 min of contact time and, thereafter, the biosorption rate decrease gradually until reaching equilibrium. The maximum sorption capacity of 17.13 and 83.89 mg g for Cr(III) ions and MB, respectively, was obtained at 40 °C, pH 5, and sorbent dose 4 g dm for removal of Cr(III) ions and 1 g dm for removal of MB. The prediction of purification process was successfully carried out, and the verification of theoretically calculated amounts of sorbent was confirmed by using packed-bed column laboratory system with recirculation of the aqueous phase. The wastewater from chrome plating industry was successfully purified, i.e., after 40 min concentration of Cr(III) ions was decreased lower than 0.1 mg dm. Also, removal of MB from the river water was successfully carried out and after 40 min, removal efficiency was about 94%.
In this study, raw and chemically activated natural zeolite from Zlatokop deposit (Serbia) were investigated by FTIR, XRD, SEM-EDX, TGA and BET in order to define their properties as further potential sorption materials. Obtained results indicate porous (meso-pore range) and defined crystal alumino-silicate structure of these materials, with Na+, K+, such as Ca2+ and Mg2+ as dominating exchangeable cations. Content of clinoptilolite (ca. 90%) indicates the high quality of the zeolite samples. Preliminary sorption analyses of these materials toward copper(II) ion from aqueous solution showed good removal efficiency for base activated zeolite (zVBB) compared to raw natural (zVBN) and acid activated (zVBA) zeolite. Since these were preliminary sorption tests, the investigated zeolites will be further
examined under different experimental conditions.
A load angle limiter was implemented as an additional function in the existing excitation system to enable the operation of the synchronous generator in the entire P-Q diagram according to the recommendation of the manufacturer of the unit B2 synchronous generator in the "Nikola Tesla B" TPP. The analysis of dynamic performance presented in this paper consists of determining the time responses and frequency characteristics of the excitation control system when the load angle limiter is active, based on which the values of the dynamic performance indexes were obtained. In addition, the paper also provides a brief description of the implementation of the limiter, as well as a description of the computer models used in the analysis.
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