Mechanochemical production of cellulose–metal NP composites requires no capping or reducing agents, and yields antibacterial and catalytically active materials.

Abstract:We report on the synthesis of Mn 3 O 4 nanoparticles (NPs) using a novel sonochemical method without requiring any pH adjustment.Synthesized material was identified as tetragonal hausmannite crystal structure model of Mn 3 O 4 from XRD analysis. Crystallite size was estimated from x-ray line profile fitting to be 17±5 nm. FTIR analysis revealed stretching vibrations of metal ions in tetrahedral and octahedral coordination confirming the crystal structure. TEM analysis revealed a dominantly cubic morphology of NPs with an average size of ~20 nm. Magnetic evaluation revealed a blocking temperature, T B of 40 K above which the material behaves paramagnetic. Asymmetric coercive field is attributed to the interaction between ferromagnetic Mn 3 O 4 and antiferromagnetic Mn oxide at the surface of nanoparticles.

The global demand for sustainable and functional fibers and textile materials is increasing with the pressure to limit the synthetic petroleum-based counterparts. In this study, we use ultrasonication for the preparation of eco-friendly cellulose fabrics bearing silver or gold nanoparticles (NPs). The mechanochemistry of cellulose is based on the breakage of glycosidic bonds and the formation of mechanoradicals. These mechanoradicals can reduce Au 3+ and Ag + ions in solution, and the reduced metals can be stabilized by the cellulose chains as nanoparticles. Here, we formed the mechanoradicals in the fabrics by sonication (on the order of 10 18 per gram), which is confirmed by ESR. The sizes and the metallic nature of NPs and the structural and morphological changes in the fabrics upon ultrasonication were studied by SEM, XPS, FTIR-ATR, XRD, and TEM. The displayed preparation method is shown to yield antibacterial AgNP-fabric and catalytically active AuNP-fabric composites, with up to a 14% yield of metal ion reduction. Since the method involves only the sonication of the fabric in aqueous solutions, and uses no hazardous reducing and stabilizing agents, it provides quick and environment-friendly access to fabric nanocomposites, which have applications in medical textiles, catalysis, and materials for energy.

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