Fungal delignification can be a feasible process to pretreat biomass for bioethanol production if its performance is improved in terms of efficiency through a few modifications. The aim of this study was to enhance the biodelignification pretreatment of rice straw using laccase in the presence of ionic liquid (1-Allyl-3-methylimidazolium chloride, [AMIM]Cl) or surfactant (TritonX-100). Addition of 750 mg/L [AMIM]Cl and 500 mg/L TritonX-100 increases the lignin removal to 18.49% and 31.79%, which is higher than that of laccase only (11.97%). The enzymatic saccharification process was carried out based on different strategies. The highest cellulose conversion, 40.96%, 38.24%, and 37.91%, was obtained after 72 h of enzymatic saccharification when the substrate was washed with distilled water after pretreatment of rice straw with laccase + TritonX-100, laccase + [AMIM]Cl, and laccase only, respectively. In addition, the morphology and structure changes of pretreated and untreated rice straw were studied. Both surface area and cellulose crystallinity are substantially altered after laccase + [AMIM]Cl and laccase + TritonX-100 pretreatment. Enhanced saccharification efficiency of rice straw was achieved by laccase pretreatment with ionic liquid or surfactant in a single system.

The Cr/Pt/Au ohmic contact resistance on n-type gallium nitrogen (GaN) is reduced by the Cl 2 inductively coupled plasma (ICP) surface treatment of n-type GaN films following laser lift-off (LLO). X-ray photoelectron spectroscopy (XPS) shows the modified atomic ratio of the n-type GaN surface following the Cl 2 ICP treatment. The Cl 2 ICP treatment increases the atomic ratio of gallium to nitrogen. GaCl x and NCl x are suggested to be generated and then removed using a boiling HCl solution. Nitrogen vacancies at the n-type GaN surface are therefore produced and act as donors for electrons, reducing ohmic contact resistance induced by reducing the resistivity of electrons to conduction.

2011) Potentially toxic trace elements accumulating in marine sediment and bivalves in the outfall area of a desalination plant, Desalination and Water Treatment, 25:1-3, 106-112 To link to this article: http://dx. ab s t r ac tThis study evaluated the environmental impact of seawater desalination effluent discharged into a water body by investigating potentially toxic trace elements in the outfall area of a desalination facility on the southeastern coast of the Penghu Island (Taiwan). Trace element concentrations are analyzed using various samples (sediment, water and bivalves). Copper, zinc and arsenic were detected in sediment samples in the outfall area and decreased progressively as one moved away from this area. A contour plotting technique was applied to assess and visualize trace element pollution point sources (inputs) in the study area. Trace element concentrations measured directly in the desalination plant effluent confirm analytical results. Bivalve samples such as oysters and clams were collected 50 m from the desalination coastal area. Trace element concentrations in bivalves varied randomly. A clear increasing tendency over time (bioaccumulation) was not observed. This study cannot support the use of trace element bioaccumulation as a bio-monitoring index for marine environments polluted by seawater desalination effluent. We recommend that investigations of bioaccumulation should be targeted close to pollution sources.

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This study used iron modified titanate nanotube arrays (Fe/TNAs) to remove E. coli in a photoelectrochemical system. The Fe/TNAs was synthesized by the anodization method and followed by the square wave voltammetry electrochemical deposition (SWVE) method with ferric nitrate as the precursor. Fe/TNAs were characterized by SEM, XRD, XPS, and UV-vis DRS to investigate the surface properties and light absorption. As a result, the iron nanoparticles (NPs) were successfully deposited on the tubular structure of the TNAs, which showed the best light utilization. Moreover, the photoelectrochemical (PEC) properties of the Fe/TNAs were measured by current-light response and electrochemical impedance spectroscopy. The photocurrent of the Fe/TNAs-0.5 (3.5 mA/cm2) was higher than TNAs (2.0 mA/cm2) and electron lifetime of Fe/TNAs-0.5 (433.3 ms) were also longer than TNAs (290.3 ms). Compared to the photolytic (P), photocatalytic (PC), and electrochemical (EC) method, Fe/TNAs PEC showed the best removal efficiency for methyl orange degradation. Furthermore, the Fe/TNAs PEC system also performed better removal efficiency than that of photolysis method in E. coli degradation experiments.