Amino acid functionalized Cu nanowire (NW) film electrode exhibits remarkably enhanced selectivity of hydrocarbons during CO2electroreduction, by stabilizing the key intermediate CHO.
Osmotically driven membrane processes (ODMPs) such as forward osmosis (FO) and pressure retarded osmosis (PRO) are extensively investigated for utilization in a broad range of applications. In ODMPs, the operating conditions and membrane properties play more critical roles in mass transport and process performance than in pressure-driven membrane processes. Search of the literature reveals that ODMP membranes, especially newly developed ones, are tested under different temperatures, draw solution compositions and concentrations, flow rates, and pressures. In order to compare different membranes, it is important to develop standard protocols for testing of membranes for ODMPs. In this article we present a standard methodology for testing of ODMP membranes based on experience gained and operating conditions used in FO and PRO studies in recent years. A round-robin testing of two commercial membranes in seven independent laboratories revealed that water flux and membrane permeability coefficients were similar when participants performed the experiments and calculations using the same protocols. The thin film composite polyamide membrane exhibited higher water and salt permeability than the asymmetric cellulosebased membrane, but results with the high permeability thin-film composite membrane were more scattered. While salt rejection results in RO mode were relatively similar, salt permeability coefficients for both membranes in FO mode were more varied. Results suggest that high permeability ODMP membranes should be tested at lower hydraulic pressure in RO mode and that RO testing be conducted with the same membrane sample used for testing in FO mode.
AbstractOsmotically driven membrane processes (ODMP) such as forward osmosis (FO) and pressure retarded osmosis (PRO) are extensively investigated for utilization in a broad range of applications. In ODMPs, the operating conditions and membrane properties play more critical roles in mass transport and process performance than in pressure-driven membrane processes.Search of the literature reveals that ODMP membranes, especially newly developed ones, are tested under different temperatures, draw solution compositions and concentrations, flowrates, and pressures. In order to compare different membranes, it is important to develop standard protocols for testing of membranes for ODMP. In this article we present a standard methodology for testing of ODMP membranes based on experience gained and operating conditions used in FO and PRO studies in recent years. A round-robin testing of two commercial membranes in seven independent laboratories revealed that water flux and membrane permeability coefficients were similar when participants performed the experiments and calculations using the same protocols. The thin film composite polyamide membrane exhibited higher water and salt permeability than the asymmetric cellulose-based membrane, but results with the high permeability thin-film composite membrane were more scattered. While salt rejection results in RO mode were...
25Wastewater nutrient recovery holds promise for more sustainable water and 26 agricultural industries. We critically review three emerging membrane processes -forward 27 osmosis (FO), membrane distillation (MD) and electrodialysis (ED) -that can advance 28 wastewater nutrient recovery. Challenges associated with wastewater nutrient recovery were 29 identified. The advantages and challenges of applying FO, MD, and ED technologies to 30 wastewater nutrient recovery are discussed, and directions for future research and 31 development are identified. Emphasis is given to exploration of the unique mass transfer 32properties of these membrane processes in the context of wastewater nutrient recovery. We 33 highlight that hybridising these membrane processes with existing nutrient precipitation 34 process will lead to better management of and more diverse pathways for near complete 35 nutrient recovery in wastewater treatment facilities. 36 3
For the first time, patterned growth of boron nitride nanotubes is achieved by catalytic chemical vapor deposition (CCVD) at 1200 °C using MgO, Ni, or Fe as the catalysts, and an Al 2 O 3 diffusion barrier as underlayer. The as-grown BNNTs are clean, vertically aligned, and have high crystallinity. Near band-edge absorption ∼6.0 eV is detected, without significant sub-band absorption centers. Electronic transport measurement confirms that these BNNTs are perfect insulators, applicable for future deep-UV photoelectronic devices and high-power electronics.
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