To clear away the harmful effects of the increment of electromagnetic pollution, high performance absorbers with appropriate impedance matching and strong attenuation capacity are strongly desired. In this study, a chain-like PPy aerogel decorated with MOF-derived nanoporous Co/C (Co/C@PPy) has been successfully prepared by a self-assembled polymerization method. With a filler loading ratio of 10 wt %, the composite of Co/C@PPy could achieve a promising electromagnetic absorption performance both in intensity and bandwidth. An optimal reflection loss value of −44.76 dB is achieved, and the effective bandwidth (reflection loss lower than −10 dB) is as large as 6.56 GHz. Furthermore, a composite only loaded with 5 wt % Co/C@PPy also achieves an effective bandwidth of 5.20 GHz, which is even better than numerous reported electromagnetic absorption (EA) materials. The result reveals that the as-fabricated Co/C@PPy—with high absorption intensity, broad bandwidth, and light weight properties—can be utilized as a competitive absorber.
In this study, Fe3O4/ZnO core–shell nanocomposites were synthesized through a chemical method of coating the magnetic core (Fe3O4) with ZnO by co-precipitation of Fe3O4 with zinc acetate in a basic medium of ammonium hydroxide. The phase structure, morphology and electromagnetic parameters of the Fe3O4/ZnO core–shell nanocomposites were investigated. The results indicated that the concentration of the solvent was responsible for controlling the morphology of the composites, which further influenced their impedance matching and microwave absorption properties. Moreover, Fe3O4/ZnO nanocomposites exhibited an enhanced absorption capacity in comparison with the naked Fe3O4 nanospheres. Specifically, the minimum reflection loss value reached −50.79 dB at 4.38 GHz when the thickness was 4.5 mm. It is expected that the Fe3O4/ZnO core–shell structured nanocomposites could be a promising candidate as high-performance microwave absorbers.
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