In this work, a high gain broadband photoconductor based on a wide bandgap amorphous gallium oxide film was reported. Meanwhile, a novel short-time heating method was demonstrated to effectively suppress the PPC effect.
Metal–organic
framework (MOF) glasses are a fascinating
new class of materials, yet their prosperity has been impeded by the
scarcity of known examples and limited vitrification methods. In the
work described in this report, we applied synergistic stimuli of vapor
hydration and thermal dehydration to introduce structural disorders
in interpenetrated
dia
-net MOF, which
facilitate the formation of stable super-cooled liquid and quenched
glass. The material after stimulus has a glass transition temperature
(T
g) of 560 K, far below the decomposition
temperature of 695 K. When heated, the perturbed MOF enters a super-cooled
liquid phase that is stable for a long period of time (>104 s), across a broad temperature range (26 K), and has a large
fragility
index of 83. Quenching the super-cooled liquid gives rise to porous
MOF glass with maintained framework connectivity, confirmed by EXAFS
and PDF analysis. This method provides a fundamentally new route to
obtain glassy materials from MOFs that cannot be melted without causing
decomposition.
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