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Shortage of water for agriculture has resulted in the need to explore the use of wastewater for irrigation, however this can pose a health problem to the people emanating from the produced food as a result of the accumulation of pollutants. The purpose of this research was to investigate the accumulation of some heavy metals and bacteriological indicators in the different parts of spinach vegetable irrigated with secondary wastewater effluent treated through a pilot filtration system. There was a variation of heavy metals accumulation in the roots, stem and leafy parts of the vegetable. Bioaccumulation factors of some metals were greater than 1 in the roots and stems but not in the leaves. Three heavy metals being copper, iron and zinc revealed high translocation factors in the stems than leaves; whereas arsenic, chromium, nickel, manganese and lead had high translocation factors in the leaves than stems. Health index coefficients in the stem during the first, second and third months were 2.33, 0.18 and 3.57 respectively, and corresponding values in the leaves were 0.68, 0.09 and 6.75 if consumed by adults. The health index values greater than 1 in children were 2.68 in the stem during the first month and then 4.1 and 7.76 in the stem and leaves during the third month for spinach consumed by children. There was no bacteriological indicators detected in the aboveground parts of the vegetable. To conclude, irrigation of vegetables should be practiced using secondary treated wastewater and monitoring over time intervals in order to safe guard human health.

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This study investigated the use of copper smelter slag for the removal of phosphorus from secondary wastewater effluent through batch tests. The media was physically and chemically characterized and showed presence of Fe 2 O 3 (45.22%), SiO 2 (14.98%), Al 2 O 3 (3.21%), CaO (1.99%), SO 3 (1.77%) and MgO (1.33%). Scanning electron microscopy monographs revealed smooth and flat surface and no heterogeneity on the surface of the slag with visible micro pores before the experiment and less visible after the experiment. The point of zero charge of the media was 5.0. Equilibrium was reached after 4 h at 29.5 AE 0.71% phosphorus removal efficiency and media dosage of 0.4/100 mL. The kinetic data was best described by Pseudo second order equation. More than one mechanisms were involved in the adsorption of phosphorus onto copper smelter slag as suggested by multilinearity of intra particle diffusion model. Ninety seven percent (97.5 AE 0.0%) removal efficiency was achieved at an equilibrium dosage of 160 gL -1 . The equilibrium isotherm was described better by Langmuir equation with observed maximum adsorption capacity of 0.16 mg P g À1 media and the experimental maximum adsorption capacity was 0.26 mg P g À1 media. Regeneration studies showed low performance with maximum efficiency of 11.7% revealed during the first regeneration trial therefore low practical benefits. Copper smelter slag is a poor adsorbent for phosphorus and further studies on the media should be conducted.