Tin-doped indium oxide (ITO) nanoparticle
(NP) films were fabricated
as a cost-effective and highly transparent electrode for high-performance
thin film heaters (TFHs), using a solution coating process on glass
substrate. The electrical and optical properties of the ITO NP films
depended on the number of spin coatings and post-annealing with various
conditions (temperature, time, and ambient gas). The optimized three
layer ITO NP films annealed at 600 °C under ambient N2 showed a low sheet resistance of 14 Ω/sq and a high optical
transmittance of 88% in the visible wavelength region of (400–800)
nm. Cross-sectional TEM images showed the ITO nanoparticles to be
evenly dispersed in the thin film with good crystallinity and well-defined
elliptical shape in the range of 10 to 25 nm. X-ray diffraction analysis
confirmed that heat treatment increased the size of the ITO NPs. The
KPFM result exhibited that as the heat treatment duration increased,
the surface roughness of the ITO NP films reduced. X-ray photoelectron
spectroscopy surface analysis showed a relatively higher area ratio
of oxygen vacancies and a more stable Sn state in the chemical states
of the O 1s and Sn 3d5/2 spectra than those of typical
ITO films deposited by a magnetron sputtering after heat treatment.
Due to the thermal stability and uniformity of the ITO NP film, ITO
NP-based TFHs showed a stable time–temperature profile and
uniform IR imagery. Therefore, solution-processed ITO NPs films can
be applied to a promising low-cost transparent electrode in the next-generation
smart window for buildings and automobiles.
Latte is a mixture of coffee and
milk and a model of complex fluids
containing biomolecules, usually leaving complex deposit patterns
after droplet evaporation. Despite the universality and applicability
of biofluids, their evaporation and deposition dynamics are not fully
understood and controllable because of the complexity of their components.
Here we investigate latte droplet evaporation and deposition dynamics,
primarily the crack development and inhibition in droplet deposit
patterns. With regard to a mixture of milk and coffee, we find that
the surfactant-like nature of milk and intermolecular interactions
between coffee particles and milk bioparticles are responsible for
achieving uniform crack-free deposits. This finding improves our understanding
of pattern formation from evaporating droplets with complex biofluids,
offering a clue to applications of bioinks with both printability
and biocompatibility.
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