We designed a nickel-assisted process to obtain graphene with sheet resistance as low as 80 Ω square(-1) from silicon carbide films on Si wafers with highly enhanced surface area. The silicon carbide film acts as both a template and source of graphitic carbon, while, simultaneously, the nickel induces porosity on the surface of the film by forming silicides during the annealing process which are subsequently removed. As stand-alone electrodes in supercapacitors, these transfer-free graphene-on-chip samples show a typical double-layer supercapacitive behaviour with gravimetric capacitance of up to 65 F g(-1). This work is the first attempt to produce graphene with high surface area from silicon carbide thin films for energy storage at the wafer-level and may open numerous opportunities for on-chip integrated energy storage applications.

Essential energy needs are not always met in poor and rural areas of developing counties; therefore, natural energy sources are necessary to mitigate this problem. Rural areas inhabitants utilize methane as a replacement for cooking gas to reduce their gas bill. Methane gas can be produced from a biogas digester; however, operating a large digester in a densely populated village in Jordan can be challenging due to inefficient village waste management systems. On the other hand, using a small-scale portable biogas digester to generate biogas could overcome these problems. In this work, three biogas digester feedstocks for a small portable biogas digester from natural sources available in Jordanian villages such as human and animal waste were designed and evaluated. The three feedstocks are food waste, human waste, and a mixture of human and food waste. The parameters tested were the digester size and the biogas production. The results showed that the best digester for portable application was that which digested a mixture of human and food waste; for a five-member family, this type of digester provided 115% of the family’s cooking gas requirements with a digester volume of 0.54 m3. This design, while applicable for a typical rural Jordanian family, can also be utilized globally.

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SummaryThe characterization of Langmuir–Blodgett thin films of 10,12-pentacosadiynoic acid (PDA) and their use in metal–insulator–metal (MIM) devices were studied. The Langmuir monolayer behavior of the PDA film was studied at the air/water interface using surface tension–area isotherms of polymeric and monomeric PDA. Langmuir–Blodgett (LB, vertical deposition) and Langmuir–Schaefer (LS, horizontal deposition) techniques were used to deposit the PDA film on various substrates (glass, quartz, silicon, and nickel-coated film on glass). The electrochemical, electrical and optical properties of the LB and LS PDA films were studied using cyclic voltammetry, current–voltage characteristics (I–V), and UV–vis and FTIR spectroscopies. Atomic force microscopy measurements were performed in order to analyze the surface morphology and roughness of the films. A MIM tunnel diode was fabricated using a PDA monolayer assembly as the insulating barrier, which was sandwiched between two nickel layers. The precise control of the thickness of the insulating monolayers proved critical for electron tunneling to take place in the MIM structure. The current–voltage characteristics of the MIM diode revealed tunneling behavior in the fabricated Ni–PDA LB film–Ni structures.

An already existing aquaponics facility in Jordan, named Khodra, will be used to evaluate the cooling and heating profiles to provide the best environment for plants and fish to thrive. A replica of the ‘Khodra’ facility will be simulated to be built in Qatar. Good ventilation rate with 50% green color shading was sufficient to reduce the temperature down by almost 10 degrees in ‘Khodra’-Jordan while using a heating, ventilation and air conditioning water-chiller based system reduced the humidity in the ‘Khodra’-Qatar greenhouse yet using AC split units was cheaper for the small size, 360 m2, of this specific greenhouse.