This paper discusses the influence of fiber reinforcement on the properties of geopolymer concrete composites, based on fly ash, ground granulated blast furnace slag and metakaolin. Traditional concrete composites are brittle in nature due to low tensile strength. The inclusion of fibrous material alters brittle behavior of concrete along with a significant improvement in mechanical properties i.e., toughness, strain and flexural strength. Ordinary Portland cement (OPC) is mainly used as a binding agent in concrete composites. However, current environmental awareness promotes the use of alternative binders i.e., geopolymers, to replace OPC because in OPC production, significant quantity of CO2 is released that creates environmental pollution. Geopolymer concrete composites have been characterized using a wide range of analytical tools including scanning electron microscopy (SEM) and elemental detection X-ray spectroscopy (EDX). Insight into the physicochemical behavior of geopolymers, their constituents and reinforcement with natural polymeric fibers for the making of concrete composites has been gained. Focus has been given to the use of sisal, jute, basalt and glass fibers.
Polyvinylidene Fluoride (PVDF) piezoelectric electrospun nanofibers have been intensively used for sensing and actuation applications in the last decade. However, in most cases, random PVDF piezoelectric nanofiber mats have moderate piezoelectric response compared to aligned PVDF nanofibers. In this work, we demonstrate the effect of alignment conducted by a collector setup composed of two-metal bars with gab inside where the aligned fiber can be formed. That is what we called static aligned nanofibers, which is distinct from the dynamic traditional technique using a high speed rotating drum. The two-bar system shows a superior alignment degree for the PVDF nanofibers. Also, the effect of added carbon nanotubes (CNTs) of different concentrations to PVDF nanofibers is studied to observe the enhancement of piezoelectric response of PVDF nanofibers. Improvement of β-phase content of aligned (PVDF) nanofibers, as compared to randomly orientated fibers, is achieved. Significant change in the piezoelectricity of PVDF fiber is produced with added CNTs with saturation response in the case of 0.3 wt % doping of CNTs, and piezoelectric sensitivity of 73.8 mV/g with applied masses down to 100 g.
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