Abstract. Despite growing evidence that the ocean is an important source of ice-nucleating particles (INPs) in the atmosphere, our understanding of the properties and concentrations of INPs in ocean surface waters remains limited. We have investigated INPs in sea surface microlayer and bulk seawater samples collected in the Canadian Arctic during the summer of 2016. Consistent with our 2014 studies, we observed that INPs were ubiquitous in the microlayer and bulk seawaters; heat and filtration treatments reduced INP activity, indicating that the INPs were likely heat-labile biological materials between 0.22 and 0.02 µm in diameter; there was a strong negative correlation between salinity and freezing temperatures; and concentrations of INPs could not be explained by chlorophyll a concentrations. Unique in the current study, the spatial distributions of INPs were similar in 2014 and 2016, and the concentrations of INPs were strongly correlated with meteoric water (terrestrial runoff plus precipitation). These combined results suggest that meteoric water may be a major source of INPs in the sea surface microlayer and bulk seawater in this region, or meteoric water may be enhancing INPs in this region by providing additional nutrients for the production of marine microorganisms. In addition, based on the measured concentrations of INPs in the microlayer and bulk seawater, we estimate that the concentrations of INPs from the ocean in the Canadian Arctic marine boundary layer range from approximately 10−4 to <10-6 L−1 at −10 ∘C.

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The objective of this study is to quantify the impact of freshwater stratification on the vertical gradients of partial pressure of CO2 (pCO2) and estimates of air-sea CO2 exchange in Hudson Bay during peak sea-ice melt and river runoff. During the spring of 2018, we sampled water in Hudson Bay and Hudson Strait for dissolved inorganic carbon, total alkalinity, salinity, the oxygen stable isotope ratio in the water (δ18O), and other ancillary data. The coastal domain and regions close to the ice edge had significant vertical concentration gradients of pCO2 across the top meters of the ocean due to the presence of a stratified fresh layer at the surface. The pCO2 and salinity in the central (where sea-ice melt was significant) and the southeast (where river runoff and sea-ice melt were significant) side of the bay generally increased with depth, with average gradients of 4.5 μatm m–1 and 0.5 m–1, respectively. Ignoring these gradients causes a significant error in calculating air-sea CO2 fluxes, especially when using shipboard underway systems that measure pCO2 at several meters below the sea surface. We found that the oceanic CO2 sink in Hudson Bay is underestimated by approximately 50% if underway pCO2 system measurements are used without correction. However, we observed that these gradients do not persist for more than 5 weeks following ice melt. We have derived a linear correction for underway pCO2 measurements to account for freshwater stratification during periods of 1–5 weeks after ice breakup. Given the lack of measurements in stratified Arctic waters, our results provide a road map to better estimates of the important role of these regions in global carbon cycles.

This study provides 6 years of high‐resolution underway measurements of the sea surface partial pressure of CO2 (pCO2sw), sea surface temperature, and salinity across the Canadian Arctic Archipelago (CAA). Observed pCO2sw varied regionally, with the northern and central channels of the CAA undersaturated in pCO2sw (with respect to the atmosphere), while the western regions were typically saturated to supersaturated in pCO2sw. This apparent spatial variability was caused to some extent by the timing of our ship transit through the CAA, as we also found a general seasonal trend of pCO2sw being undersaturated in the early summer, followed by saturation to supersaturation in late summer, and a return to undersaturation during the autumn. Sea surface temperature was significantly correlated with pCO2sw at various locations across the CAA, but we also observed the effects of other regional processes like upwelling, primary production, riverine input, and sea ice melt. These processes are linked to each other, and hence, it is impossible to pinpoint only one dominant factor controlling pCO2sw variability in the CAA. However, we found that sea ice dominates the seasonal cycle of all these processes, thus making the timing of sea ice breakup a useful predictor of pCO2sw variability in the CAA. We calculated an average net oceanic sink of 14 mmol CO2 · m−2 · day−1 for the CAA during the summer and autumn seasons, but caution that a more rigorous budgeting approach is required to fully account for biases in dates and locations of our measurements.