No abstract

Due to their excellent properties, polymides (PIs) result promising as high-performance materials in different technological fields. In this research, both micron-sized tubular mesoporous silica (mSiO2) and double-tube tubular diatomite particles with cadmium sulfide quantum dots are prepared by chemical deposition method. A cluster of type fluorescent particles is prepared by self-assembling carbon quantum dots (CDs) on the inner surface of the above materials. Then, a fluorescent polyimide film is prepared by uniform dispersion of fluorescent particles. The study of different properties of the film becomes then mandatory to evaluate possible application perspectives. Therefore, after synthesizes, all samples were investigated in term of chemical structure, microstructure and fluorescence properties by infrared spectroscopy, x-ray diffraction, scanning electron microscopy and fluorescence spectrophotometry. Fluorescence performance of diatomite-based fluorescent particles (diatomite@CdS@CDs) results not as good as the mSiO2-based fluorescent particles (mSiO2@CdS@CDs) ones; the mechanical properties of the composite film deteriorate as the content of the inorganic component increases. The performance of PI/mSiO2@CdS@CDs is 7.6 times the PI/diatomite@CdS@CDs ones.