This report deals with converting the agriculture waste (rice straw) to environmental cleaner materials (biochar) using airless pyrolysis followed by eco-friendly activation. The biochar (p-Biochar) obtained after pyrolysis step (poorly active material) was activated using wet attrition method to give m-Biochar (highly active materials). The both p-Biochar and m-Biochar were characterized in detail and utilized for MB and CV dye removal from aqueous solution. Various parameters affecting the adsorption process such as dye concentration, adsorbent dose, contact time, temperature, NaCl dose and pH were investigated. The adsorption isotherm was well fitted using Langmuir isotherm, and the maximum adsorption capacity is 90.91 and 44.64 mg/g, for MB and CV dyes, respectively. The contact time data obtained showed that the two dyes were poorly adsorbed over p-Biochar. The equilibrium was reached quickly in 15 min for MB dye and 20 min for CV dye using the m-Biochar, and removal percent was 94.45 and 92.70% for MB and CV dyes, respectively. Moreover, the kinetic isotherm presented very well fitted by pseudo-second-order model. In addition, the adsorption percent increases with further increasing the pH value. Finally, we observed that m-Biochar highly adsorbs the MB dye compared with the CV dye over all experimental conditions.
Evapotranspiration (ET) is one of the biggest data gaps in water management due to limited ET measurements, and further, spatial variability in ET is difficult to capture. Satellite-based ET estimation has great potential for water resources planning as it allows estimation of agricultural water use at field, landscape, and watershed scales. However, uncertainties with satellite data derived ET are a major concern. This study evaluates hourly satellite-based ET from 2001–2010 for the growing season (May–October) under irrigated and dryland conditions for both tall and short crops. The evaluation was conducted using observed ET from four large weighing lysimeters at the United States Department of Agriculture Agricultural Research Service (USDA-ARS) Conservation and Production Research Laboratory in Bushland, Texas. Hourly ET from satellite data were derived using the Mapping Evapotranspiration at High Resolution with Internalized Calibration (METRIC) model. Performance statistics showed that satellite-based hourly estimates compared to lysimeter measurements provided good performance with an root-mean-square error(RMSE) of 0.14 mm, Nash–Sutcliffe efficiency (NSE) of 0.57, and R2 of 0.62 for ET for dryland crops, and RMSE of 0.16, NSE of 0.63, and R2 of 0.65 for irrigated crops. METRIC provided accurate hourly ET estimates that may be useful for irrigation scheduling and other water resources management purposes based on the hourly assessment.
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