Surface sediments of the lagoons of Lomé, Togo, were analyzed for mercury, methylmercury, and trace elements. Concentrations were greater than typical for natural lagoon sediments, and with greater variability within the Eastern lagoon compared to the Western one. The Eastern lagoon is larger and has been dredged in the past, while the Western lagoon, which also receives major waste inputs, has not been dredged and shows less tidal flushing. Accordingly, one naturally believes that the Eastern lagoon is cleaner and probably safe to use due to its natural resources, including fishes to eat. Unexpectedly, we describe here that mercury methylation was greater in the Eastern lagoon, indicating increased bioavailability of mercury, as probably facilitated by past dredging that decreased solidphase retention of inorganic mercury. Urbanization has historically been more developed in the southern part of the lagoons, which is still reflected in contamination levels of sediment despite dredging, probably because sources of contamination are still more important there today. Such urban contamination emphasizes the need to regulate waste discharges and possible airborne contamination in growing cities of developing countries, and implements environmental and public health monitoring, especially in relation to misbelieves systematically associated with the cleansing effect of dredging activity.

Sediment core samples were collected from the Salinas de San Pedro to assess the pollutant deposition processes in response to extensive human activities. Analysis of the sediment samples for heavy metals and some trace elements was conducted with ICP-OES for 20 sites showing enrichment for some of trace and heavy metals. The results demonstrated that heavy metal concentrations in mud varied greatly for each metal, with concentration values (mg/g) ranging from 1.05 - 4.8 (Al); 0.003 - 0.011(As); 0.001 - 0.005 (Cd); 0.02 to 0.82 (Cr); 0.085 - 0.47 (Cu); 5.98 - 14.22 (Fe); 0.06 - 0.19 (Mn); 0.03 - 0.67 (Ni); 0.05 - 0.38 (Pb); <0.008 - 0.069 (Se); 0.18 - 0.63 (Ti); 0.040 - 0.091 (V) and 0.149 - 0.336 (Zn). The Index of Geo-accumulation factor showed highest values for Pb, Mn, As, and Cu. Enrichment factors >1for these elements suggest anthropogenic inputs for most metals. The bioavailability of metals in lagoon sediments has the potential to be highly dynamic with local waste and natural H₂S discharge from existing fault line.

Abstract

In this project, we will present the findings of a study using Tensiometer systems designed to investigate the water flow path pattern in shallow vadose zone. The purpose of this paper is to evaluate water flow path in shallow vadose zone and to calculate the infiltration rate and hydraulic conductivity of a soil using Tensiometer. We have measured the subsurface water flow paths in sandy clay loam soil following infiltration experiment using Tensiometers. The matric potential and hydraulic conductivity measurements show that subsequent infiltration and water movement in unsaturated (vadose) zone are vertical, but it can have large lateral component under steady condition. This shows that water moves generally from high water content to lower water content region. Average pressure head for the percolation test conduction locations EB and HB was −30 and −80 cm respectively. Hysteresis produces another interesting situation when the soil is drained. We found that the wetter portion of the soil in vadose zone could be at a lower potential (head) than the dryer portions, resulting in lateral driving force for a preferential flow of water from the dryer to the wet soil. The infiltration rate for the 5 cm ponded water was calculated at 5.45 cm/hr. The infiltration rate curve shows that the rate of infiltration decreases with the time. When infiltration first starts, the wetting front is steep and very close to the surface. Similarly, due to the pressure head gradient, large value for infiltration is recorded. Under these conditions, we believe that the gradient in pressure head is responsible for the rapid movement of water into the dry soil. The effect of gravity is less on water during the initial stages of infiltration; however, it is more effective for preferential flow pattern. In the latter infiltration event, the wetting front has moved deeper into the soil. As a result, the pressure head gradient at the surface is much smaller and consequently has little effect.

The coastal wetland, Ballona Lagoon in Southern California has experienced degradation and size reduction due to urbanization. This study analyzes nitrate concentrations in the lagoon to identify contamination sources and assess its impact. The study includes determining nitrate levels during high and low tides during wet and dry seasons, establishing concentration gradients, and examining the relationship between salinity and nitrate concentrations. The nitrate concentrations were found to be higher in locations closer to the head of the lagoon, particularly in urbanized areas, suggesting land-based sources during the dry season's high tide (S2: 2.37 mg/l; S3: 3.85 mg/l; S4: 3.91 mg/l). Findings highlight the importance of managing nitrate contamination near urban areas. Monitoring nitrate levels over time are crucial for sustainability efforts. This research emphasizes the need for long-term monitoring and conservation strategies to mitigate nitrate contamination in Ballona Lagoon.