No abstract

Anatase and amorphous TiO2 nanoparticles were used to improve recovery of heavy oil from sandstone cores. Before performing core floods, the stability of nanoparticles at different salinities was tested using ζ potential and ultraviolet–visible (UV–vis) methods. While water recovered only 49% of the oil in the core flood experiments, 0.01% anatase structure solution recovered 80% of the oil after injecting two pore volumes at optimum conditions. To understand the mechanism responsible for improved recovery, contact angle measurements were performed on the rock surface before and after treatment with the nanoparticle solution. Contact angle measurements showed that the rock wettability changed from oil-wet to water-wet conditions after treatment with nanoparticles. In 0.01% concentration, scanning electron microscopy (SEM) results showed homogeneous deposition of nanoparticles onto the core plug surface and a few nanorods with a diameter about 60 nm were observed. Energy-dispersive spectrometry (EDS) confirms diffusion of nanoparticles in porous media and uniform distribution. When the nanoparticle concentration was increased, more nanorods with the same diameter were composed, which resulted in plugging to occur. These results indicated the possibility of TiO2 application in enhanced oil recovery (EOR); however, more investigation is required to overcome multi-nanoparticle deposition onto pores.

No abstract

Interfacial tension (IFT) as one of the main properties for efficient CO2 flooding planning in oil reservoirs depends strongly on pressure, temperature, and composition of the reservoir fluids. Therefore, it is important to measure this property at real reservoir conditions for successful field development plan. In this study, an axisymmetric drop shape analysis (ADSA) has been utilized to measure the equilibrium IFTs between crude oil and CO2 at different temperatures and pressures. Moreover, minimum miscibility pressures (MMP) and first-contact miscibility pressures (P max) of crude oil/CO2 systems at different temperatures are determined by applying the vanishing interfacial tension (VIT) technique. Besides, the effects of paraffins content and resin to asphaltene ratio of the crude oil on the IFT behavior are investigated. The results show that while the IFT has a decreasing trend with temperature at low pressures region, it has an increasing trend with temperature at high pressures. Also, MMP and P max were found to increase linearly with temperature. The results indicate that paraffin has a critical effect on the crude oil/CO2 IFT behavior. It was also found that the lower the ratio of resin-to-asphaltene is, the more is the possibility of asphaltene precipitation as determined by examining the IFT behavior of the solution. Moreover, the results verified that the higher is the molecular weight of heavier components of the crude oil, the higher are the MMP values obtained.

No abstract