Fluid fine tailings (FFTs) generated
by the surface mining of oil
sand ore bodies are high-water-content, clay-rich materials that contain
unrecovered bitumen and additional residual organics, including solvents
used during bitumen extraction. Despite a large accumulated inventory
of these tailings and despite the environmental implications and challenges
that the presence of organics poses, little is known about the differences
in the residual organics generated by different bitumen extraction
processes and about the effects of polymeric flocculation on mineral–organic
interactions. This study investigated residual organics in two compositionally
different FFTs both before and after flocculation with a commercially
available polyacrylamide polymer. Thermogravimetric (TG) analysis,
Fourier transform infrared (FTIR) spectroscopy, and evolved gas analysis
(EGA-TG-FTIR) were used to characterize the makeup of total organics,
free bitumen, and mineral-associated organics. These observations
highlighted distinct differences between the FFTs. Relative to the
sample receiving waste only from the bitumen extraction process (FFT-1),
the FFT sample that received waste from both the extraction and the
froth treatment processes (FFT-2) exhibited a higher residual organic
content and a larger fraction of lower-molecular-mass organic substances
and showed a proportionally smaller release of free bitumen as a result
of the washing process, evidence of a higher fraction of mineral-associated
organics. Moreover, TG and FTIR analyses showed that the free bitumen
released from both FFTs contained a higher fraction of lighter organics
and was characterized by a more ordered molecular structure compared
to the remaining organics. Finally, the study also found that the
bitumen release characteristics of FFT-1 were fundamentally different
from those of FFT-2. Bitumen release continued to be observed from
both FFTs after polymeric flocculation.
This paper investigates the load–displacement characteristics of rammed aggregate piers (RAPs) by applying the innovative idea of simulating the ramming procedure of the aggregates as a fully dynamic process. High radial stresses, induced by ramming, play an important role in the load–settlement behaviour of RAPs. Previously, two simplifying assumptions have been used for considering the effects of ramming in the numerical simulations of RAPs by researchers: (a) prescribed displacement of the cavity wall, and (b) prescribed volumetric strain of the cavity. The dynamic method in this paper, which simulates the cavity expansion in separate lifts, offers a useful option for the analysis of the cases in which the exact amount of the increase of the cavity diameter is not known earlier such as for RAP design purposes or evaluation of a completed project installed on RAPs. A parametric study is conducted using this method to investigate the effects of various parameters such as embedment depth, decreased compaction energy and soil friction angle on the behaviour of RAPs. A simple design method is then provided along with the design charts based on the results of the parametric study.
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