A methodology based on inductively coupled plasma optical emission spectroscopy (ICP-OES) after microwave assisted acid digestion has been developed to determine the trace element content of Moroccan argan oil. Limit of detection values equal or lower than few mg/kg were obtained for all elements under study. To assure the accuracy of the whole procedure, recovery studies were carried out on argan oil samples spiked at different concentration levels from 10 to 200 µg/L. Quantitative average recovery values were obtained for all elements evaluated, demonstrating the suitability of this methodology for the determination of trace elements in argan oil samples. Aluminum, calcium, chromium, iron, potassium, lithium, magnesium, sodium, vanadium and zinc were quantitatively determined in Moroccan argan oils being found that their concentration is different of that found in other edible oils thus offering a way for authentication and for the evaluation of possible adulterations.
This study aimed to determine the total arsenic concentration in lipsticks and evaluate the potential health risks due to daily ingestion of this toxic element from this product. The samples were analyzed using atomic fluorescence spectrometry technique after mineralization and hydride generation (HG-AFS). The calibration curve is linear over a concentration range from 0.125 to 2 µg L-1 with a regression coefficient of the order of 0.9899. The limit of detection is reaches 3 ng g-1. The standard deviation is of the order of 4%.The accuracy of this method was evaluated by calculating the recoveries of additions of arsenic to three lipstick samples. These results indicate recovery rates between 91% and 98%. Finely, the results found demonstrate that the method used in this work is suitable for arsenic detection in lipsticks samples.
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