The performance of hybrid fillers between rice husk and sawdust filled recycled high density polyethylene (rHDPE) with the presence of antioxidants (IRGANOX 1010 and IRGAFOS 169, with the ratio of 1 : 1) was investigated. The biocomposites with 30 wt% of matrix and around 70 wt% of hybrid fillers (rice husk and sawdust) and different antioxidants' contents (0 to 0.7 wt%) were prepared with single screw extruder. Increasing the amount of antioxidants in biocomposites reduced the modulus of elasticity and modulus of rupture on flexural testing. The addition of antioxidants increased the tensile and impact strength of biocomposites. From the study, samples with 0.5 wt% of antioxidants produce the most reasonable strength and elasticity of biocomposites. Furthermore, the effect of antioxidants content on water uptake was minimal. This might be caused by the enhanced interfacial bonding between the polymer matrix and hybrid fillers, as shown from the morphology by using scanning electron microscopy (SEM).
A novel H 2 sensor using tapered optical fiber coated with Pd/ZnO nanostructures have been developed. The ZnO nanostructures was synthesized and deposited onto tapered optical fiber via chemical bath deposition (CBD) method. The ZnO was characterized by FESEM, XRD and EDX to confirm the material properties. It was discovered that the sensor is sensitive towards different concentrations of H 2 in synthetic air at 180° C of operating temperature. By varying the deposition time of ZnO coating, different thickness of ZnO layer can be obtained. It was observed that with 280 nm thickness, the maximum absorbance response can be achieved. Further investigation with sensor sample of as-prepared and annealed was carried out to study its sensing performance towards H 2 . The absorbance response of 280 nm thickness of annealed Pd/ZnO has increased 64% as compared to as-prepared Pd/ZnO upon 1% H 2 exposure in the synthetic air when measured in the visible to near infra-red optical wavelength. It can be concluded that the Pd/ZnO optical fiber sensor with thickness around 280 nm provided better sensitivity in sensing H 2 at 180°C as compared to other thicknesses investigated.
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