Coagulation/flocculation is a major phenomenon occurring during industrial and municipal water treatment to remove suspended particles. Common coagulants are metal salts, whereas flocculants are synthetic organic polymers. Those materials are appreciated for their high performance, low cost, ease of use, availability and efficiency. Nonetheless, their use has induced environmental health issues such as water pollution by metals and production of large amounts of sludges. As a consequence, alternative coagulants and flocculants, named biocoagulants and bioflocculants due to their biological origin and biodegradability, have been recently developed for water and wastewater treatment. In particular, chitosan and chitosan-based products have found applications as bioflocculants for the removal of particulate and dissolved pollutants by direct bioflocculation. Direct flocculation is done with water-soluble, ionic organic polymers without classical metalbased coagulants, thus limiting water pollution. Chitosan is a partially deacetylated polysaccharide obtained from chitin, a biopolymer extracted from shellfish sources. This polysaccharide exhibits a variety of physicochemical and functional properties resulting in numerous practical applications. Key findings show that chitosan removed more than 90% of solids and more than 95% of residual oil from palm oil mill effluents. Chitosan reduced efficiently the turbidity of agricultural wastewater and of seawater, below 0.4 NTU for the latter. 99% turbidity removal and 97% phosphate removal were observed over a wide pH range using 3-chloro-2-hydroxypropyl trimethylammonium chloride grafted onto carboxymethyl chitosan. Chitosan also removed 99% Microcystis aeruginosa cells and more than 50% of microcystins. Here, we review advantages and drawbacks of chitosan as bioflocculant. Then, we present examples in water and wastewater treatment, sludge dewatering and post-treatment of sanitary landfill leachate.

The drying suction – water content soil-water characteristic curves (SWCCs) of three clays (MX80 bentonite, yellow bentonite, and Speswhite kaolin) were experimentally determined using axis-translation, vapour equilibrium, and osmotic techniques. The shrinkage paths of the clays were established from Clod tests. The suction – water content SWCCs in conjunction with the Clod test results enabled establishing the suction – degree of saturation SWCCs and further determination of the air-entry values (AEVs) of the clays. Chemical analyses of the polyethylene glycol (PEG) solutions in the osmotic tests revealed an imbalance of the osmotic suctions between the expelled and the retained salts on either side of semi-permeable membranes. A decrease in the water content due to an applied suction for clays with significant osmotic efficiencies was explained by two mechanisms. In mechanism 1, the water content decrease prior to the air entry is controlled by the interparticle repulsive pressure, and in mechanism 2, a decrease in the degree of saturation following the air entry is primarily due to the matric suction. The agreements between the AEVs of the clays determined based on the osmotic suctions corresponding to various applied suctions and that determined from the suction – degree of saturation SWCCs were found to be very good.

In the laboratory, semi-permeable membranes and polyethylene glycol (PEG) solutions are used for applying suction in soils using the osmotic technique. In this study, the pore structures of cellulose semi-permeable membranes with molecular weight cut-off values of 3500 and 14 000 were examined via an atomic force microscope (AFM). Fourier transform infrared (FTIR) spectroscopy was used to identify any degradation of PEG molecules with elapsed time. Freshly prepared PEG solutions and solutions aged for 15 days were considered for this purpose. Osmotic tests were carried out on initially saturated MX80 bentonite specimens at two suction levels (0?44 and 7?04 MPa). Comparison of the AFM images of the semi-permeable membranes before and after the osmotic tests clearly revealed that the pore size of the semi-permeable membranes increased significantly, particularly at the higher applied suction that enabled passing of PEG molecules into the clay specimens. FTIR spectrums of PEG 20 000 and PEG 6000 did not provide any evidence of degradation of the PEG molecules with elapsed time.

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Lateritic soils at Universiti Teknologi Malaysia (UTM) Skudai, Malaysia was investigated subjected to their geotechnical properties and their suitability to be used as construction materials. The soil samples were collected and tested for various basic soil properties tests such as Atterberg Limit, Specific Gravity (SG), Sieve Analysis, and Compaction test. Atterberg’s consistency limit test shows that the liquid limit (LL) is 70.3%, the plastic limit (PL) is 42.0%, and the plasticity index (PI) is 28.3%. The specific gravity (SG) value for laterite is 2.74. For the compaction test, the optimum moisture content (OMC) and maximum dry density (MDD) obtained are 28% and 1.39 g/cm 3. A laboratory study was performed to compare and evaluate the stabilization efficiency of different percentages (3%, 6%, 9%, 12%) of Ordinary Portland Cement (OPC) when applied to the available laterite soil; a major soil group in the tropical areas. Analysis of laboratory data is assessed from a soil compaction test through the standard proctor method by using the automatic compactor. The soil mixtures were compacted at optimum moisture content in accordance with the British Standard (BS) of BS 1377-4:1990. From the preceding results, it was found that the OMC increase from 28% to 34% while the MDD increase from 1.39 g/cm³ to 1.47 g/cm³ with the rise in the percentage of cement.