Thermo-gravimetric and differential thermo-gravimetric analyses were performance to study the effect of temperature on the mineralogical compositions of rice husk ash subjected to different grinding time. Eight rice husk ashes with different grinding time, i.e. coarse original rice husk ash (RHA0), RHA1, RHA2, RHA3, RHA4, RHA5, RHA6, and RHA7 were used for the study. The TGA/ DTA analysis and X-ray fluorescence (XRF) was used through this investigation. On the other hand, the pozzolanic activity index of the RHA was assessed in accordance with ASTM C 311-11a. From the experiment, it was found that the greater the weight loss, the less the crystallinity of the RHA. In addition, there are no significant differences in chemical compositions of the rice husk ashes with different grinding time. Furthermore, when the grinding time increased from 1 hour and 30 minutes to 5 hours, there was a significant drop in the pozzolanic index.
The rainfall measurement can be done by using rain gauge and weather radar instruments. However, weather radar does not measure the rainfall depth directly as contrary to rain gauge. Therefore, an empirical relationship between reflectivity (Z) and rainfall rate (R) which is commonly known as reflectivity-rainfall (Z-R) relationship consisting of parameter A and exponential b (Z= A·Rb
), usually used to convert reflectivity data into rainfall rate for a radar. Presently, the Z-R relationship parameters proposed by Marshall and Palmer (1947) used in Malaysia is seem no longer suitable for Malaysia condition. Hence, a new relationship should be developed. The reflectivity data from year 2006 to year 2007 at Alor Setar radar and gauge rainfall data from 14 rain gauge in the Northern of Peninsular Malaysia were calibrated. By using the Traditional Matching Method (TMM), a new parameter was developed for Alor Setar radar which located in Northern Peninsular Malaysia. By minimizing the errors, a Mean Field Bias Correction (MFB) technique was apply to all selected parameter in this study with adjusting the value A and fixed the value b. As a results, new climatological Z-R relationship (Z=14.30R
1.9) was obtained. To justify the new relationship, validation analysis has been performed by using the five statistical measure. It was found that the validation analysis has given the best results of Mean Error (ME), Mean Absolute Error (MAE), Root Mean Square Error (RMSE), Bias and Pearson Correlation Coefficient (r) with value of 0.00, 0.00, 7.54, 1.00 and 0.85 respectively. Concluded that, it is suitable for radar rainfall estimation in the Northern Region of Peninsular Malaysia.
Moringa oleifera was tested as a coagulant for its excellent coagulating properties in the treatment of water and wastewater. Moringa oleifera is a tropical plant belonging to the family of Moringaceae, besides being a non-toxic and natural organic polymer. The aim of this study is to investigate the removal of chemical oxygen demand (COD) from landfill leachate using Moringa oleifera through a coagulation-flocculation process. In this study, Moringa oleifera was used as a coagulant. Jar test experiments were employed in order to determine the optimum conditions of coagulant dosage and pH. The conditions of Moringa oleifera dosage of 20 mL and pH 2 were found to be optimal in the effective treatment of the landfill leachate. The study has proven that Moringa oleifera is a good natural coagulant for water treatment. Furthermore, only a small quantity of Moringa oleifera is required in treating a large amount of leachate.
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