The uptake of Benzene onto modified solid materials have been reported most commonly with abrupt peripheral application of the defining models based chiefly on regression parameter validation. This paper considered a perspective application of mainly the empirical kinetic models of predetermined applicability as well as their parent nature to contemporary kinetic models. Verification of the applicable kinetic mechanisms defined by 1 2  f), the Langmuirian uptake is better in the PSO domain. The transfer of benzene sorptive for uptake was complementarily controlled first by internal diffusion then by film diffusion.