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The technology of polymer microtips’ manufacturing on the ends of selected multi-mode fibers has been reported. The study’s key element was an extended description of technology parameters’ influence on the shape of these 3D microstructures. Basic technology parameters such as spectral characteristics of the light source, monomer mixture type, optical power, and exposure time were taken under consideration. Depending on those parameters, different shapes, sizes, and surface structures of microtips were obtained. The spectral characteristics of the light and optical power delivered to a monomer drop were identified as the most important parameters for the formation of the desired 3D shape of the microtip. Presented experimental results are the base for further studies directed to the application of these micro-elements in the fields of optical measurements and sensors’ technology.

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A polymer microtip manufactured at the end of a multi-mode optical fiber by using the photopolymerization process offers good reflective properties, therefore, it is applicable as an optical fiber sensor micro-transducer. The reflective properties of this microelement depend on the monomer mixture used, optical fiber type, and light source initiating polymerization. Experimental results have shown that a proper selection of these parameters has allowed the design of a new class of sensing structure which is sensitive to the refractive index (RI) changes of a liquid medium surrounding the microtip. An optical backscatter reflectometer was applied to test a group of micro-transducers. They were manufactured from two monomer mixtures on three different types of multi-mode optical fibers. They were polymerized by means of three optical light sources. Selected micro-transducers with optimal geometries were immersed in reference liquids with a known RI within the range of 1.3–1.7. For a few sensors, the linear dependences of return loss and RI have been found. The highest sensitivity was of around 208 dB/RIU with dynamic 32 dB within the range of 1.35–1.48. Sensing characteristics have minima close to RI of a polymer microelement, therefore, changing its RI can give the possibility to tune sensing properties of this type of sensor.