CN 74 ± 7 4.3 ± 0.4 X 107 a From T0bsd-1 = tl-1 + #csq [B]. 6 To be compared with tl = 27 s and Lsq = 1.25 X 108 M~' s'1, ref 3f. 1 Note that this is a corrected value for that previously reported by us as 5.5 qs. d To be compared with tl = 10 ± 1 qs and ksQ = 1.6 X 105 M~' s'1, ref 3g. e To be compared with ksQ = 3.25 X 105 M'1 s'1, ref 3g. / From benzene quenching data in Table II using the relationship tl'1 kq(Q) where (Q) 12 M.
Die Geschwindigkeitskonstanten der Selbstlöschung, ksl?, der Benzophenone (I) in Benzol und CCl4 korrelieren mit den Hammett‐Konstanten 0 diskontinuierlich mit negativem Anstieg bei X = Elektronendonator Minimum bei X = ‐H, ‐F, ‐Cl, und positivem Anstieg bei X = Elektronenacceptor.
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