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Neutral heteroleptic trinuclear coordination cages containing a preorganized well-defined small spherical endocavity, which is made up of electron-deficient bowl frameworks, three coordination-induced neutral polar C−H donors, and a phenyl motif, were self-assembled via a one-pot approach; the endocavity accommodates fluoride selectively in the presence of other halides.

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Double ouroboros-shaped molecular dimer was crystallized from tripodal molecule having ability to adopt conformation similar to molecular tweezers at one end and a lone unit at other. Two complementary tripodal...

No abstract