We suggest to employ the dissipative nature of open quantum systems for the purpose of parameter estimation: the dynamics of open quantum systems is typically described by a quantum dynamical semigroup generator . The eigenvalues of  are complex, reflecting unitary as well as dissipative dynamics. For certain values of parameters defining , non-Hermitian degeneracies emerge, i.e. exceptional points (EP). The dynamical signature of these EPs corresponds to a unique time evolution. This unique feature can be employed experimentally to locate the EPs and thereby to determine the intrinsic system parameters with a high accuracy. This way we turn the disadvantage of the dissipation into an advantage. We demonstrate this method in the open system dynamics of a two-level system described by the Bloch equation, which has become the paradigm of diverse fields in physics, from NMR to quantum information and elementary particles.

Markovian dynamics of open quantum systems are described by the L-GKS equation, known also as the Lindblad equation. The equation is expressed by means of left and right matrix multiplications. This formulation hampers numerical implementations. Representing the dynamics by a matrix-vector notation overcomes this problem. We review three approaches to obtain such a representation. The methods are demonstrated for a driven two-level system subject to spontaneous emission.

We consider population transfer in open quantum systems, which are described by quantum dynamical semigroups (QDS). Using second order perturbation theory of the Lindblad equation, we show that it depends on a weak external field only through the field's autocorrelation function, which is phase independent. Therefore, for leading order in perturbation, QDS cannot support dependence of the population transfer on the phase properties of weak fields. We examine an example of weak-field phase-dependent population transfer, and show that the phase-dependence comes from the next order in the perturbation.

Abstract. We suggest a method for accurate parameter estimation of atomic systems, employing the special properties of the exceptional points. The non-hermitian degeneracies at the exceptional points emerge from the description of the spontaneous emission of atomic system in the framework of an open quantum system, resulting in a non hermitian quantum master equation. The method is demonstrated for the atomic spectrum of S → P transitions of 85 Rb and 40 Ca + .

Detonation of a three-dimensional reactive nonisotropic molecular crystal is modeled using molecular dynamics simulations. The detonation process is initiated by an impulse, followed by the creation of a stable fast reactive shock wave. The terminal shock velocity is independent of the initiation conditions. Further analysis shows supersonic propagation decoupled from the dynamics of the decomposed material left behind the shock front. The dependence of the shock velocity on crystal nonlinear compressibility resembles solitary behavior. These properties categorize the phenomena as a weak detonation. The dependence of the detonation wave on microscopic potential parameters was investigated. An increase in detonation velocity with the reaction exothermicity reaching a saturation value is observed. In all other respects the model crystal exhibits typical properties of a molecular crystal.