Highly efficient light-emitting diodes (LEDs) emitting ultraviolet (UV), blue, green, amber and red light have been obtained through the use of InGaN active layers instead of GaN active layers. Red LEDs with an emission wavelength of 675 nm, whose emission energy was almost equal to the band-gap energy of InN, were fabricated. The dependence of the emission wavelength of the red LED on the current (blue shift) is dominated by both the band-filling effect of the localized energy states and the screening effect of the piezoelectric field. In the red LEDs, a phase separation of the InGaN layer was clearly observed in the emission spectra, in which blue and red emission peaks appeared. In terms of the temperature dependence of the LEDs, InGaN LEDs are superior to the conventional red and amber LEDs due to a large band offset between the active and cladding layers. The localized energy states caused by In composition fluctuation in the InGaN active layer contribute to the high efficiency of the InGaN-based emitting devices, in spite of the large number of threading dislocations and a large effect of the piezoelectric field. The blue and green InGaN-based LEDs had the highest external quantum efficiencies of 18% and 20% at low currents of 0.6 mA and 0.1 mA, respectively.
We markedly improved the extraction efficiency of emission light from the InGaN-based light-emitting diode (LED) chips grown on sapphire substrates. Two new techniques were adopted in the fabrication of these LEDs. One is to grow nitride films on the patterned sapphire substrate (PSS) in order to scatter emission light. Another is to use the Rh mesh electrode for p-GaN contact instead of Ni/Au translucent electrode in order to reduce the optical absorption by the p-contact electrode. We fabricated near-ultraviolet (n-UV) and blue LEDs using the above-mentioned techniques. When the n-UV (400 nm) LED was operated at a forward current of 20 mA at room temperature, the output power and the external quantum efficiency were estimated to be 22.0 mW and 35.5%, respectively. When the blue (460 nm) LED was operated at a forward current of 20 mA at room temperature, the output power and the external quantum efficiency were estimated to be 18.8 mW and 34.9%, respectively.
We fabricated a phosphor-conversion white light emitting diode (LED) using an InGaN chip that emits 400 nm near-ultraviolet (n-UV) light and phosphors that emit in the blue and yellow region. When the white LED was operated at a forward-bias current of 20 mA at room temperature (RT), the color temperature (T cp ), average color rendering (R a ), operating voltage (V f ) and luminous efficacy (η L ) were estimated to be 5800 K, 85.3, 3.2 V, and 26.1 lm/W, respectively. With increasing forward-bias current, the luminous flux increased almost linearly and was estimated to be 5.0 lm at 60 mA. The Commission Internationale de l'Eclairage (CIE) chromaticity coordinates obtained from the measured spectra remained almost constant during the forwardbias current increase from 0.5 mA to 60 mA.
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