Regenerated cellulose films were prepared with environmentally friendly process by utilized N-methylmorpholine-N-oxide (NMMO)-Cellulose system. To prepare a dense cellulose film for membrane application, some parameter process which influence porous forming such as cellulose DP, cellulose concentration, addition NMMO in coagulation bath, coagulation bath temperature, and drying condition were investigated. We resumed that the porosity and pore size of cellulose membrane decrease with lower cellulose DP, higher cellulose concentration, addition of NMMO in coagulation bath, applying room temperature in coagulation bath and drying, and applying vacuum on drying process resulted in membranes with porosity in range of 24-41% and pore size 13.4-20.2 nm. The main factor for controlling porosity and pore size of dense cellulose membrane was coagulation process condition especially addition of NMMO into coagulation bath.