Geo-electric soundings was carried out in 22 different locations at Kaduna Refinery Petrochemical Corporation (KRPC) and White Oil and Gas Layout, Mahuta, Kaduna. The aquifer protective capacity and Hydraulic characteristics of the study area was computed from the Geoelectric parameters using Dar-Zarrouk and hydrological parameters. The interpreted data were presented in tabular form, Geoelectric/geology soil profiles and contoured maps. The results show that the study area aquifer is relatively protected with an average value of 0.5 mhos with an indication of infiltration of contaminant in some location. The hydraulic parameter values also show that the study area aquifer has the capacity to produce water non-stopping if the wells are sited based the geophysical investigation. The computed hydraulic characteristics and transmissivity of the area has an average value of 5.5 m/day and 6.1 /hour, which implies that, the study area has the capacity to transmit groundwater through a distance of 5.5 m in 24-hour and can covers 6.1  in one hour.

Water security is the central mission of the sustainable development goals. The demand for potable and clean water has skyrocketed due to frequent borehole failures and population expansion, which requires adequate groundwater resource management strategies. Identifying groundwater potential zone, overburden protective index capacity and installations of alternative/artificial storage support mechanisms for water security and sustainability under the growing water challenge and demand is critical. This study identifies; (i) aquifer promising zones (ii) aquifer protective capacity through geophysical investigation and suggests (iii) improving aquifer recovery management strategy as the top three targets for groundwater development. An electric resistivity technique was applied to acquire a total of sixty (60) vertical electrical sounding points with Schlumberger arrays. The study indicates the resistivity layer of the aquifer unit ranges from 21 to 294 Ωm, while the aquifer layer thickness values spread from 8 to 59 m and the overburden thickness overlays the aquifer unit extends from 3 to 20 m. The deeper aquifer zones were encountered between 30 and 59 m, which could be suitable for groundwater development, and the shallow aquifer occurs between 8 and 14 m, which is not encouraging for groundwater development and may be susceptible to surface contaminations. However, for water security and sustainability, multiple boreholes should be sited at the delineated aquifer promising zone where the aquifer is fractured and occurs within a depth of 30 m and above. The weathered/fractured units constitute the regional aquifer units, which are largely responsible for the groundwater potential. The hydraulic conductivity of the regional aquifer was estimated to vary between 0.337 and 10.62 m/day, which invariably enhances the aquifer recovery processing. Groundwater quality and the risk of surface contamination were examined through overburden protective index capacity.

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In this research paper, a HTM-free perovskite solar cell (PSC) structure with Titanium (TiO2), methyl ammonium lead triiodide (CH3NH3PbI3) and platinum (pt) as electron transport material (ETM), photon harvester and metal back contact is proposed. Solar Cell Capacitance Simulator (SCAPS-1D) program was used to implement the model and simulation. Effect of parameters such as thickness of ETM, thickness of absorber, doping concentration of ETM & absorber and electron affinity (EA) of ETM were investigated systematically. From the obtained results, it was found that the parameters affect the performance of the solar cell. When the thickness of ETM was varied from 0.02 to 0.10 μm. The results show that photovoltaic parameters decrease with the thickness increase. When the thickness of the absorber was varied from 0.1 to 1.0 μm, the optimized value was found at thickness of 0.4 . When the doping concentration of absorber and EMT were varied from 1010–1017 cm-3 and from 1015–1020 cm-3, the highest values of PCEs were obtained at 1016 cm-3 and 1020 cm-3 for Absorber and ETM. Also when the EA was varied in the range of 3.7 eV to 4.5 eV, the optimized value was at 3.7 eV. Upon optimization of the above mentioned parameters, power conversion efficiency (PCE) was found to be 25.75 %, short circuit current density (Jsc) 23.25 mAcm-2, open circuit voltage (Voc) 1.24 V and fill factor (FF) 89.50 %. The optimized result shows an improvement of ~1.95 times in PCE, ~1.06 times in Jsc, ~1.44 times in Voc and ~1.28 times in FF as compared to the initial device with the following parameters, PCE=13.22 %, Jsc=21.96 mAcm−2, Voc=0.86 V and FF=69.94 %.