Recently,
synthesis, characterization, and application of carbon dots have received much attention. Natural
products are the effectual carbon precursors to synthesize carbon
dots with fascinating chemical and physical properties. In this study,
the fluorescent sensor of carbon dots derived from cranberry beans
without any functionalization and modification was developed. The
carbon dots were prepared with a cheap, facile, and green carbon precursor
through a hydrothermal treatment method. The synthetic process was
toxic chemical-free, convenient, and environmentally friendly. To
find the optimized synthetic conditions, the temperature, heating
time duration, and carbon precursor weight were evaluated. The prepared
carbon dots were characterized by UV light, transmission electron
microscopy, Raman, Fourier transform infrared, UV–vis, and
fluorescence spectroscopy. The resulting carbon dots exhibit stable
fluorescence with a quantum yield of approximately 10.85%. The carbon
dots emitted the broad fluorescence emission range between 410 and
540 nm by changing the excitation wavelength and were used for the
detection of Fe3+ ions at the excitation of 380 nm. It
is found that Fe3+ ions induced the fluorescence intensity
quenching of the carbon dots stronger than other heavy metals and
the Fe3+ ion detection can be achieved within 3 min. Spectroscopic
data showed that the obtained carbon dots can detect Fe3+ ions within the wide concentration range of 30–600 μM
with 9.55 μM detection limit.
Carbon dots (CDs) are a new cluster of carbon atoms with particle size less than 10 nm. CDs also exhibit interesting fluorescence (FL) properties. CDs are attractive because of their fascinating characteristics including low toxicity, good water solubility, and tremendous biocompatibility. Recently, CDs have been investigated as biosensors for numerous target analytes. Meanwhile, the utilization of cheap and renewable natural resources not only fulfills the pressing requirement for the large-scale synthesis of CDs but also encourages the establishment of sustainable applications. The preparation of CDs using natural resources, i.e., plants, offers several advantages as it is inexpensive, eco-friendly, and highly available in the surroundings. Plant parts are readily available natural resources as the starting materials to produce CDs with different characteristics and attractive applications. Several review articles are now available covering the synthesis, properties, and applications of CDs. However, there is no specific and focused review literature discussing plant part-derived CDs for biosensing applications. To handle this gap, we provide a review of the progress of CDs derived from various plant parts with their synthesis methods, optical properties, and biosensing applications in the last five years. We highlight the synthesis methods and then give an overview of their optical properties and applications as biosensors for various biomolecules and molecules in biological samples. Finally, we discuss some future perspectives for plant part-derived CDs for better material development and applications.
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