The present paper describes the first successful application of poultry waste chicken feathers in the development of green, biodegradable, and eco-friendly lubricant additives. The additive was synthesized through three step chemical functionalization of chicken feathers. The first step involves the reaction between chicken feather powder (CF) and (3-aminopropyl)trimethoxysilane (APTMS) to synthesis CF-APTMS, the second step involves the synthesis of CF-Schiff base by reacting CF-APTMS with 3,5-ditert-butyl-4-hydroxybenzaldehyde, and in the third step, esterification with lauroyl chloride catalyzed by 4-(dimethylamino)pyridine (DMAP) afforded the final product acylated chicken feather Schiff base. The applicability of this CF derived additive as a biodegradable and ecofriendly lubricating oil additive was investigated by testing the antioxidant, lubricity, and anticorrosion properties in polyol which was taken as a reference base fluid. A rotatary bomb oxidation test (RBOT) was used to evaluate the antioxidant characteristics while a four ball test was employed for the tribological properties. The additive is found to be very effective as an antioxidant and anticorrosive additive, but as an antiwear additive its potential is moderate.
Magnetically separable poultry chicken feathers were found to be efficient, green and heterogeneous catalyst for oxidation of alcohols and sulfides to the corresponding carbonyl compounds and sulfoxides, respectively using t-butyl hydroperoxide (TBHP) as oxidant with complete selectivity and higher conversions. The developed catalyst exhibited higher stability, activity and better recycling ability than the bare magnetic nanoparticles. The designed catalyst could readily be recovered by external magnet without showing any significant leaching during the reaction.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.