Tunable plasmonic resonance induced by the collective oscillation of the electrons on metallic nanostructures can excellently enhance the light response of ZnO films, which provides an effective way to break through the limitation of the performance of ZnO photodetectors. Here, broad-band high-performance ZnO/Au heterostructures photodetectors with various morphologies of self-assembled Au nanoantennas are fabricated via a facile approach under the spin-coated ZnO colloidal quantum dots films. With a systematic control on growth condition, the self-assembled Au nanoantennas undergo a drastic evolution from the corrugated nanomounds to the island-like nanostructures, and the light absorption of the resulting ZnO/Au heterostructures correspondingly exhibits a strongly morphological dependence on the Au nanoantennas. Meanwhile, the photoresponse of the ZnO-based photodetectors is significantly improved throughout a wide spectrum between UV and visible regions owing to the enhanced light absorption induced by the localized surface plasmon resonance. As a result, the optimal switch ratio of the ZnO/Au heterostructures photodetector increases by 1 order to ∼1.13 × 10 than that of the pristine ZnO one because of the obviously increased photocurrent ( I) and comparable dark current, thus leading to ∼9.1 and ∼4.9 times increases in the photoresponsivity and the normalized detectivity. Meanwhile, the significant increases in the I of ∼5.2 and ∼9.7 times are likewise observed with the ZnO/Au heterostructures under 530 nm and white-light illumination. This work can offer a handy and effective approach for the fabrication of ultrasensitive ZnO-based photodetectors within a broad-band wavelength by utilizing the Au plasmonic nanostructures.

Strong near‐surface electromagnetic field formed by collective oscillation of electrons on Cu nanostructure a shows a strong dependence on geometry, offering a promising approach to boost the light absorption of ZnO photoactive layers with enhanced plasmon scattering. Here, a facile way to fabricate UV photodetectors with tunable configuration of the self‐assembled Cu nanostructures on ZnO thin films is reported. The incident lights are effectively confined in ZnO photoactive layers with the existence of the uplayer Cu nanostructures, and the interdiffusion of Cu atoms during fabrication of the Cu nanostructures can improve the carrier transfer in ZnO thin films. The optical properties of the hybrid architectures are successfully tailored over a control of the geometric evolution of the Cu nanostructures, resulting in significantly enhanced photocurrent and responsivity of 2.26 mA and 234 A W−1 under a UV light illumination of 0.62 mW cm−2 at 10 V, respectively. The photodetectors also exhibit excellent reproducibility, stability, and UV–visible rejection ratio (R370 nm/R500 nm) of ≈370, offering an approach of high‐performance UV photodetectors for practical applications.

SERS spectroscopy aims to augment the relatively weak molecular vibrations based on electromagnetic and chemical enhancement mechanisms, and offers a potential way for material identification, even up to the single-molecule level, under atmospheric conditions.

The resonantly enhanced near-surface electromagnetic field of Al nanostructures (NSs) excited with UV light offers an effective and precise approach to obtain vibration information in complex mixtures up to a single-molecule magnitude.