Magnetic iron oxide and iron/copper nanoparticles were synthesized using Lathyrus brachypterus extract, and then magnetic Fe 3 O 4 –CS, Fe 3 O 4 –AT, Fe/Cu–CS and Fe/Cu–AT nanocomposite beads were synthesized using chitosan and alginate natural polymers. They were used for both adsorption and heterogeneous catalysts for the catalytic wet peroxidation (CWPO) of naproxen (NPX), diclofenac (DCF) and NPX + DCF drugs which are important micro-organic pollutants, separately and together (NPX + DCF) from aqueous media. In adsorption studies, the drugs were adsorbed very quickly in the first minutes and then, desorbed in between 8 and 10 min. In competitive adsorption, the adsorbents showed selective properties for DCF and NPX. In CWPO technique, drug removal was achieved in 9 min with a conversion capacity of 92% for DCF with Fe/Cu–CS and 84% for NPX with Fe/Cu–AT optimum experimental conditions, such as pH 5, 30% of H 2 O 2 , 100 mg catalyst and 298 K. Based on reusability of the catalysts, it was seen that there was a slight decrease in the removal efficiencies in the third cycle and the stable and active structure of the catalyst was preserved to the desired extent. Furthermore, the oxidation reaction was in good agreement with the pseudo-first-order kinetic model. Graphical abstract

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Synthesis, characterization, Pb(II) adsorption, recovery, preconcentration and reusability of different nanoadsorbents were investigated in detail. With green synthesis, silver, iron oxide and iron copper nanoparticles (AgNPs, Fe3O4NPs and Fe/CuNPs) were synthesized and modified with chitosan and alginate natural polymers to form nanocomposite beads (Fe3O4‐CS, Fe3O4−AT, Fe/Cu−CS and Fe/Cu−AT). When the adsorption efficiencies of the seven synthesized nanoadsorbents from the aqueous medium were compared, it was seen that the magnetic bimetallic Fe/Cu−CS beads provided the highest adsorption with 100 % efficiency for Pb(II). The adsorption mechanism, effects of temperature, initial lead ion concentration and pH of the solution on the Pb(II) adsorption capacity of Fe/Cu−CS beads were investigated. The recovery studies have shown that Fe/Cu−CS beads have good adsorption/desorption performance around 90 % of desorption was achieved with 5 mM HNO3. These results show that Fe/Cu−CS beads have potential to be a promising material for adsorption, preconcentration and desorption of Pb(II) from aqueous solution.